3,4,5-三甲氧基甲苯合成路线 （共 96 条）
反应条件
sulfuric acid; dihydrogen peroxide; acetic acid
参考文献
Wang, Jin; Yang, Jian; Yang, Bo; Sun, Jia-Qiang; Yang, Tao
Journal of Chemical Research, 2010 , vol. 34, # 12 p. 724 - 725
反应条件
1: With dihydrogen peroxide; toluene-4-sulfonic acid; acetic acid T=75°C; 0.5 h; 2: With nitric acid in water T=0 - 5°C; 0.00833333 h;
参考文献
Occhipinti, Giovanni; Liguori, Lucia; Tsoukala, Anna; Bjorsvik, Hans-Rene
Organic Process Research and Development, 2010 , vol. 14, # 6 p. 1379 - 1384
反应条件
sulfuric acid; 3,3-dimethyldioxirane in acetone T=20°C; 2 h;
参考文献
Synthesis, , # 6 p. 560 - 562
反应条件
1: 95 percent / POCl3 / 5 h / 65 °C 2: aq.H2SO4; aq.H2O2 / methanol / 10 - 20 °C 3: 17.6 g / benzene; polyglycol-400; aq.NaOH / H2O / 2.5 h / 55 °C / pH 9.0 - 9.5 View Scheme
参考文献
Wang, Jin; Yang, Jian; Yang, Bo; Hu, Xiao; Sun, Jia-Qiang; Yang, Tao
Journal of Chemical Research, 2010 , vol. 34, # 12 p. 717 - 718
反应条件
potassium in tetrahydrofuran 24 h; Ambient temperature;
参考文献
Azzena, Ugo; Denurra, Teresa; Melloni, Giovanni; Rassu, Gloria
Journal of the Chemical Society, Chemical Communications, 1987 , p. 1549 - 1550
反应条件
1: 82.7 percent / POCl3 / 1 h / 90 °C 2: 78.3 percent / BCl3 / CH2Cl2 / 2.5 h / -78 °C View Scheme
参考文献
Aquila,H.
Justus Liebigs Annalen der Chemie, 1969 , vol. 721, p. 220 - 222
反应条件
anhydrous iron chloride in chlorobenzene T=80°C; Friedel Crafts Acylation; 6 h;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2004/54953 A1, 2004 ;
Location in patent: Page 6 ;
反应条件
graphite in 1,2-dichloro-ethane
参考文献
BASF Corporation
Patent: US2001/31753 A1, 2001 ;
反应条件
sodium hydroxide; bromine; sodium acetate; acetic acid; P2 O5; dichloromethane in ethanol; water
参考文献
American Cyanamid Company
Patent: US5922905 A1, 1999 ;
反应条件
sodium hydroxide; bromine in tetrachloromethane; ethanol; dichloromethane; water
参考文献
American Cyanamid Company
Patent: US5922905 A1, 1999 ;
