1,2,3,4-四乙基苯合成路线 （共 22 条）
反应条件
1: Cp2TiCl2 With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: hex-3-yne in tetrahydrofuran; hexane T=-10°C; 3 h; 3: 4-fluorobenzenecarbonitrile in tetrahydrofuran; hexane 1 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
1: Cp2TiCl2 With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: hex-3-yne in tetrahydrofuran; hexane T=-10°C; 3 h; 3: benzonitrile in tetrahydrofuran; hexane T=50°C; 12 h;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
1: Cp2TiCl2 With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: hex-3-yne in tetrahydrofuran; hexane T=-10°C; 3 h; 3: 4-cyanotoluene in tetrahydrofuran; hexane 1 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
1: Cp2TiCl2 With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: hex-3-yne in tetrahydrofuran; hexane T=-10°C; 3 h; 3: n-butyronitrile in tetrahydrofuran; hexane 1 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
1: hex-3-yne With n-butyllithium; zirconocene dichloride in tetrahydrofuran; hexane T=-78 - 20°C; 3 h; 2: trans vinyl bromide With NiCl2((PPh3)P)2 in tetrahydrofuran; hexane T=20°C; 1 h;
参考文献
Zhou, Xin; Li, Zhiping; Wang, Hui; Kitamura, Masanori; Kanno, Ken-Ichiro; Nakajima, Kiyohiko; Takahashi, Tamotsu
Journal of Organic Chemistry, 2004 , vol. 69, # 13 p. 4559 - 4562
反应条件
1: Cp2TiCl2 With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: hex-3-yne in tetrahydrofuran; hexane T=-10°C; 3 h; 3: benzonitrile-α-13C in tetrahydrofuran; hexane 1 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
hydrogenchloride; barytes; sulfuric acid T=170°C; Reaktion ueber mehrere Stufen;
参考文献
Chemische Berichte, , vol. 21, p. 2815
反应条件
1: (d5-cyclopentadienyl)(methylcyclopentadienyl)titanium dichloride With n-butyllithium in tetrahydrofuran T=0°C; 2: hex-3-yne in tetrahydrofuran T=-78°C; 1 h; 3: benzonitrile in tetrahydrofuran 1 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 125, # 32 p. 9568 - 9569
反应条件
aluminium trichloride T=145 - 150°C;
参考文献
Journal of the American Chemical Society, , vol. 63, p. 3514,3516
反应条件
1: AlCl3; chlorosulfonic acid; alcoholic NaOH-solution / 170 °C / Reagens 4: konz. Salzsaeure; Reaktion ueber mehrere Stufen 2: barytes; concentrated hydrochloric acid; concentrated sulfuric acid / 170 °C / Reaktion ueber mehrere Stufen View Scheme
参考文献
Chemische Berichte, , vol. 21, p. 2815
