1,2-双(二乙基磷)乙烷合成路线 （共 9 条）
反应条件
1: diethyl phosphine With cesium hydroxide monohydrate in N,N-dimethyl-formamide T=20°C; 1 h; Molecular sieveInert atmosphere; 2: ethylene dibromide in N,N-dimethyl-formamide T=20°C; 72 h; Inert atmosphereMolecular sieve;
参考文献
US2010/137669 A1, ;
Page/Page column 12 ;
反应条件
(i) Li, THF, (ii) /BRN= 605264/, Et2O; Multistep reaction;
参考文献
Journal of the Chemical Society, , p. 1490 - 1494
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 40, # 5 p. 624 - 635
参考文献
Organometallics, , vol. 6, p. 1260 - 1267
反应条件
in toluene Schlenk techniques used; protective gas: N2; detailed description given; depe was added to stirred soln. of W(CO)3PMTA; reflux (1 h); cooling; intermediate fac-isomer detected by IR spectroscopy;; filtration (through alumina); evapn.; recrystn. (CH2Cl2/hexane/-20°C); elem. anal.:;
参考文献
Zanotti, Valerio; Rutar, V.; Angelici, Robert J.
Journal of Organometallic Chemistry, 1991 , vol. 414, # 2 p. 177 - 191
反应条件
2,2'-azo-bisisobutyronitrile T=75°C; 16 h;
参考文献
GE HEALTHCARE LIMITED; HJELSTUEN, Ole, Kristian
Patent: WO2006/64175 A1, 2006 ;
Location in patent: Page/Page column 17 ;
反应条件
in tetrahydrofuran T=50°C; 2 h; Thermodynamic data;
参考文献
Canadian Journal of Chemistry, , vol. 79, # 5-6 p. 626 - 631
反应条件
in acetone Irradiation (UV/VIS); under Ar or N2, irradn. of soln.; 1H NMR spectroscopy;
参考文献
Inorganic Chemistry, , vol. 26, p. 253 - 258
反应条件
in tetrahydrofuran T=50°C; 2 h; Thermodynamic data;
参考文献
Smith D.C.; Cadoret; Jafarpour; Stevens; Nolan
Canadian Journal of Chemistry, 2001 , vol. 79, # 5-6 p. 626 - 631
