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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
63723-85-3
合成路线
(共 6 条)
67-66-3
氯仿
+
63723-85-3
→
反应条件
63723-86-4
+
23346-81-8
+
65223-12-3
+
65223-14-5
反应条件
sodium hydroxide; trimethylhexadecylammonium chloride in dichloromethane 3 h; Ambient temperature; Further byproducts given;
参考文献
Sato, Masaru; Inaba, Keiko; Ebine, Seiji; Tsunetsugu, Josuke
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 8 p. 2334 - 2339
67-66-3
氯仿
+
63723-85-3
→
反应条件
63723-86-4
+
23346-81-8
+
65223-14-5
+
65223-13-4
反应条件
sodium hydroxide; trimethylhexadecylammonium chloride in dichloromethane 3 h; Ambient temperature; Further byproducts given;
参考文献
Sato, Masaru; Inaba, Keiko; Ebine, Seiji; Tsunetsugu, Josuke
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 8 p. 2334 - 2339
67-66-3
氯仿
+
63723-85-3
→
反应条件
63723-86-4
+
23346-81-8
+
65223-14-5
+
65223-15-6
反应条件
sodium hydroxide; trimethylhexadecylammonium chloride in dichloromethane 3 h; Ambient temperature; Further byproducts given;
参考文献
Sato, Masaru; Inaba, Keiko; Ebine, Seiji; Tsunetsugu, Josuke
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 8 p. 2334 - 2339
75-25-2
三溴甲烷
+
63723-85-3
→
反应条件
23346-81-8
反应条件
sodium hydroxide; trimethylhexadecylammonium chloride in dichloromethane 1.5 h; Ambient temperature; Further byproducts given;
参考文献
Sato, Masaru; Inaba, Keiko; Ebine, Seiji; Tsunetsugu, Josuke
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 8 p. 2334 - 2339
63723-84-2
+
77-78-1
硫酸二甲酯
→
反应条件
63723-85-3
反应条件
sodium hydroxide in methanol T=60°C; 1 h;
参考文献
Sato, Masaru; Inaba, Keiko; Ebine, Seiji; Tsunetsugu, Josuke
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 8 p. 2334 - 2339
18798-66-8
→
反应条件
63723-85-3
反应条件
1: 1.) BuLi, 2.) tributyl borate, 3.) 10percent HCl, 4.) 30percent H2O2 2: 94 percent / NaOH aq. / methanol / 1 h / 60 °C View Scheme
参考文献
Sato, Masaru; Inaba, Keiko; Ebine, Seiji; Tsunetsugu, Josuke
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 8 p. 2334 - 2339