二(1-甲基乙基)苯基膦合成路线 （共 13 条）
反应条件
ammonia; sodium T=-78°C; 4 h; Title compound not separated from byproducts;
参考文献
Doorn, Johannes A. van; Meijboom, Nico
Recueil des Travaux Chimiques des Pays-Bas, 1992 , vol. 111, # 4 p. 170 - 177
反应条件
(i) Li, THF, (ii) H2O; Multistep reaction;
参考文献
Grim,S.O.; Molena,R.P.
Phosphorus and the Related Group V Elements, 1974 , vol. 4, p. 189 - 193
反应条件
lithium in tetrahydrofuran
T=25°C; 16 h; Yield given;
参考文献
Doorn, Johannes A. van; Meijboom, Nico
Recueil des Travaux Chimiques des Pays-Bas, 1992 , vol. 111, # 4 p. 170 - 177
反应条件
ammonia; sodium
T=-78°C; 4 h; Title compound not separated from byproducts;
参考文献
Doorn, Johannes A. van; Meijboom, Nico
Recueil des Travaux Chimiques des Pays-Bas, 1992 , vol. 111, # 4 p. 170 - 177
反应条件
in pentane
T=-78°C; 2.5 h; Yields of byproduct given;
参考文献
Neuffer, J.; Richter, W. J.
Journal of Organometallic Chemistry, 1986 , vol. 301, p. 289 - 298
反应条件
in pentane
T=-40 - 25°C; 14 h;
参考文献
Neuffer, J.; Richter, W. J.
Journal of Organometallic Chemistry, 1986 , vol. 301, p. 289 - 298
反应条件
magnesium in diethyl ether
T=20°C; Inert atmosphere;
参考文献
Tukacs, Jozsef M.; Kiraly, David; Stradi, Andrea; Novodarszki, Gyula; Eke, Zsuzsanna; Dibo, Gabor; Kegl, Tamas; Mika, Laszlo T.
Green Chemistry, 2012 , vol. 14, # 7 p. 2057 - 2065
反应条件
1: 57 percent / pyridine / toluene
2: 77 percent / diethyl ether; benzene / 16 h / -40 °C
3: pentane / 14 h / -40 - 25 °C
View Scheme
参考文献
Neuffer, J.; Richter, W. J.
Journal of Organometallic Chemistry, 1986 , vol. 301, p. 289 - 298
反应条件
in benzene-d6
T=80°C; P=760.051 Torr; 2 h; Inert atmosphere;
参考文献
Fong, Henry; Moret, Marc-Etienne; Lee, Yunho; Peters, Jonas C.
Organometallics, 2013 , vol. 32, # 10 p. 3053 - 3062
反应条件
1: 77 percent / diethyl ether; benzene / 16 h / -40 °C
2: pentane / 14 h / -40 - 25 °C
View Scheme
参考文献
Neuffer, J.; Richter, W. J.
Journal of Organometallic Chemistry, 1986 , vol. 301, p. 289 - 298
