反应条件
1.1: 1H-imidazole / tetrahydrofuran / 5 h / 20 °C / |Inert atmosphere 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 15 h / 20 °C / |Inert atmosphere 3.1: triethylamine; 4-(N,N-dimethlyamino)pyridine / dichloromethane / 1 h / 0 - 20 °C / |Inert atmosphere 4.1: bis(cyclopentadienyl)titanium dichloride; cis-IrCl(CO)(PPh3)2; manganese; 2,4,6-trimethyl-pyridine; chloro-trimethyl-silane; hydrogen / tetrahydrofuran / 4 h / 20 °C / 3000.3 Torr 5.1: triethylamine; 4-(N,N-dimethlyamino)pyridine / dichloromethane / 2 h / 0 - 20 °C / |Inert atmosphere 6.1: (1S)-10-camphorsulfonic acid / methanol / 3 h / 0 - 20 °C / |Inert atmosphere 7.1: triphenylphosphine / tetrahydrofuran / 0.25 h / 20 °C / |Inert atmosphere 7.2: 0.17 h / -10 °C / |Inert atmosphere 7.3: 4 h / -10 °C / |Inert atmosphere 8.1: formic acid / 9 h / 50 °C / |Inert atmosphere 9.1: sodium methylate / methanol / 0.5 h / 20 °C / |Inert atmosphere View Scheme
参考文献
Velasco, Javier; Ariza, Xavier; Badia, Laura; Bartra, Marti; Berenguer, Ramon; Farras, Jaume; Gallardo, Joan; Garcia, Jordi; Gasanz, Yolanda
Journal of Organic Chemistry, 2013 , vol. 78, # 11 p. 5482 - 5491
