2-(N,N-dimethylamino)-pyridine; palladium (II) trifluoroacetate; oxygen; toluene-4-sulfonic acid in dimethyl sulfoxide T=80°C; P=760.051 Torr; 24 h;

1: phenol With potassium hydroxide in toluene T=50°C; 0.166667 h; 2: With carbon dioxide T=190°C; P=19001.3 Torr; 2 h; Inert atmosphereAutoclave; 3: 4-phenyliodobenzene With PEPPSI-IPr catalyst; acetic acid; silver carbonate T=130°C; P=19001.3 Torr; 16 h; Inert atmosphereAutoclave; Reagent/catalyst; regioselective reaction;

in 1-methyl-pyrrolidin-2-one; dimethyl sulfoxide T=80°C; 36 h;

1: [Pd(CH3CN)4](BF4)2; 6,6'-dimethyl-2,2'-bipyridine; anthraquinone-2-sulfonic acid sodium salt; oxygen / 1-methyl-pyrrolidin-2-one / 13 h / 50 °C / 760.05 Torr 2: dimethyl sulfoxide; 1-methyl-pyrrolidin-2-one / 36 h / 80 °C View Scheme

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