3,4,6-三-O-乙酰基-1,2-O-亚乙基吡喃己糖合成路线 （共 7 条）
反应条件
potassium hydroxide in toluene 3.5 h; Heating;
参考文献
Du, Yuguo; Kong, Fanzuo
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 3 p. 341 - 352
反应条件
methanol; sodium methylate T=20°C; 4 h;
参考文献
Gorska, Katarzyna; Huang, Kuo-Ting; Chaloin, Olivier; Winssinger, Nicolas
Angewandte Chemie, International Edition, 2009 , vol. 48, # 41 p. 7695 - 7700
反应条件
sodium tetrahydroborate; tetra-(n-butyl)ammonium iodide in acetonitrile
T=20°C; 24 h;
参考文献
Huang, Shengshu; Yu, Hai; Chen, Xi
Angewandte Chemie - International Edition, 2007 , vol. 46, # 13 p. 2249 - 2253
反应条件
sodium tetrahydroborate in acetonitrile
T=0 - 20°C; 2 h; Cooling with ice; Optical yield = 5 percent de;
参考文献
Giordano, Maddalena; Iadonisi, Alfonso
European Journal of Organic Chemistry, 2013 , # 1 p. 125 - 131
反应条件
2,2'-azo-bisisobutyronitrile; tributyltin chloride; sodium cyanoborohydride in tert-butyl alcohol
0.833333 h; Irradiation;
参考文献
Praly, Jean-Pierre; Ardakani, Azin Salek; Bruyere, Isabelle; Marie-Luce, Chrystelle; Bing Qin, Bing
Carbohydrate Research, 2002 , vol. 337, # 18 p. 1623 - 1632
反应条件
1: iodine / dichloromethane / 0.17 h / |Reflux
2: sodium tetrahydroborate / acetonitrile / 2 h / 0 - 20 °C / |Cooling with ice
View Scheme
参考文献
Giordano, Maddalena; Iadonisi, Alfonso
European Journal of Organic Chemistry, 2013 , # 1 p. 125 - 131
反应条件
1: I2; triethylsilane / CH2Cl2 / Heating
2: sodium borohydride / acetonitrile / 20 °C
View Scheme
参考文献
Adinolfi, Matteo; Iadonisi, Alfonso; Ravida, Alessandra; Schiattarella, Marialuisa
Tetrahedron Letters, 2003 , vol. 44, # 43 p. 7863 - 7866
