Gilman et al.
Recueil des Travaux Chimiques des Pays-Bas, 1935 , vol. 54, p. 588
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Gilman; Brown
Journal of the American Chemical Society, 1930 , vol. 52, p. 3315
in tetrahydrofuran
addn. of dry THF to Hg2Cl2 (4 mmol) in three-necked flask (flushed with Ar); cooling to -50°C; dropwise addn. of soln. of C4H9ZnI (10 mmol) in THF; stirring for 0.5 h at -50°C, warming to room temp.; stirring for 2 h;; addn. of aq. NH4Cl, extg. with ether (3 times); washing combined org. layers succesively with H2O and brine, drying over MgSO4; evapg. solvents; flash chromy. (hexane) of crude product; purity 95percent (2percent (C6H13)2Hg impurity);;
参考文献
Rozema, Michael J.; Rajagopal, Duddu; Tucker, Charles E.; Knochel, Paul
Journal of Organometallic Chemistry, 1992 , vol. 438, # 1.2 p. 11 - 27
Wilde
Journal of the Chemical Society, 1949 , p. 72,75
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Melnikow
Zhurnal Obshchei Khimii, 1946 , vol. 16, p. 2065,2067
Chem.Abstr., 1948 , p. 877
Wilde
Journal of the Chemical Society, 1949 , p. 72,75
Full Text Show Details
Melnikow
Zhurnal Obshchei Khimii, 1946 , vol. 16, p. 2065,2067
Chem.Abstr., 1948 , p. 877
