2-甲基-1,2,4-丁三醇合成路线 （共 9 条）
反应条件
Amberlyst A 26 (CO32- form) in benzene
6 h; Heating;
参考文献
Bongini, Alessandro; Cardillo, Giuliana; Orena, Mario; Porzi, Gianni; Sandri, Sergio
Journal of Organic Chemistry, 1982 , vol. 47, # 24 p. 4626 - 4633
反应条件
1: K2CO3; mCPBA / CH2Cl2 / 21 h / 20 °C
2: H2 / Pd/C / methanol; CH2Cl2 / 20 h
3: H2O / H2SO4 / tetrahydrofuran
View Scheme
参考文献
Steinreiber, Andreas; Osprian, Ingrid; Mayer, Sandra F.; Orru, Romano V. A.; Faber, Kurt
European Journal of Organic Chemistry, 2000 , # 22 p. 3703 - 3711
反应条件
1: H2 / Pd/C / methanol; CH2Cl2 / 20 h
2: H2O / H2SO4 / tetrahydrofuran
View Scheme
参考文献
Steinreiber, Andreas; Osprian, Ingrid; Mayer, Sandra F.; Orru, Romano V. A.; Faber, Kurt
European Journal of Organic Chemistry, 2000 , # 22 p. 3703 - 3711
反应条件
2: 92 percent / Amberlyst A 26 (OH- form) / methanol / 2 h / Ambient temperature
3: 84 percent / Amberlyst A 26 (CO32- form) / benzene / 6 h / Heating
View Scheme
参考文献
Bongini, Alessandro; Cardillo, Giuliana; Orena, Mario; Porzi, Gianni; Sandri, Sergio
Journal of Organic Chemistry, 1982 , vol. 47, # 24 p. 4626 - 4633
反应条件
1: 92 percent / Amberlyst A 26 (OH- form) / methanol / 2 h / Ambient temperature
2: 84 percent / Amberlyst A 26 (CO32- form) / benzene / 6 h / Heating
View Scheme
参考文献
Bongini, Alessandro; Cardillo, Giuliana; Orena, Mario; Porzi, Gianni; Sandri, Sergio
Journal of Organic Chemistry, 1982 , vol. 47, # 24 p. 4626 - 4633
反应条件
osmium(VIII) oxide; sodium perchlorate in tetrahydrofuran
参考文献
Barner; Schmid
Helvetica Chimica Acta, 1979 , vol. 62, # 7 p. 2384 - 2399
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
2 h; Heating;
参考文献
Masaki, Yukio; Arasaki, Hideki; Shiro, Motoo
Chemistry Letters, 2000 , # 10 p. 1180 - 1181
反应条件
lithium aluminium tetrahydride
参考文献
Sakito, Yoji; Asami, Masatoshi; Mukaiyama, Teruaki
Chemistry Letters, 1980 , p. 455 - 458
参考文献
Sakito, Yoji; Asami, Masatoshi; Mukaiyama, Teruaki
Chemistry Letters, 1980 , p. 455 - 458
