1: n-butyllithium With indium(III) chloride in tetrahydrofuran
T=-78 - 20°C;
2: 4-tert-butyl-1-cyclohexen-1-yl trifluoromethanosulfonate With bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
1 h; Heating; Further stages.;
参考文献
Perez, Ignacio; Sestelo, Jose Perez; Sarandeses, Luis A.
Organic Letters, 1999 , vol. 1, # 8 p. 1267 - 1269
1: sec-butylmagnesium chloride With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: 1-chloro-4-(1,1-dimethylethyl)-1-cyclohexene With 1-methyl-pyrrolidin-2-one; Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran
T=100°C; Negishi reaction; 5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
