反应条件
1.1: AlCl3, aluminium chloride / dichloromethane / 2.5 h / 0 - 20 °C / |Inert atmosphere 2.1: norborn-2-ene; palladium diacetate; triphenylphosphine; caesium carbonate / 12 h / 80 °C 3.1: titanium tetraethoxide / tetrahydrofuran / 0.17 h / 0 °C / |Inert atmosphere 3.2: 24 h / 60 °C / |Inert atmosphere 4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / -78 °C / |Inert atmosphere; |Heating 5.1: hydrogenchloride; water / methanol / 4 h / 0 - 20 °C / |Inert atmosphere 6.1: palladium 10 on activated carbon; hydrogen / ethyl acetate; acetic acid / 24 h / 45 °C / 2068.65 Torr 7.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 - 20 °C / |Inert atmosphere 8.1: triethylamine / dichloromethane / 1 h / 20 °C 9.1: potassium phtalimide / N,N-dimethyl-formamide / 1 h / 100 °C 9.2: 3 h / |Reflux 10.1: triethylamine / dichloromethane / 20 °C View Scheme
参考文献
Fu, Xiaodan; Guo, Xingqun; Li, Xingwei; He, Lidong; Yang, Yushe; Chen, Youxi
Tetrahedron Asymmetry, 2013 , vol. 24, # 13-14 p. 827 - 832