hydrogenchloride; zinc in water
T=100°C; 3 h; Overall yield = 63 percent; Overall yield = 2.58 g;
参考文献
Lyall, Catherine L.; Uosis-Martin, Mario; Lowe, John P.; Mahon, Mary F.; Pantos, G. Dan; Lewis, Simon E.
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 9 p. 1468 - 1475
1.1: phosphorous pentoxide; phosphoric acid / 0.17 h / 150 °C
1.2: 3 h / 140 °C
2.1: ozone / acetonitrile; dichloromethane / 1.5 h / -10 °C
2.2: 1 h / 20 °C
3.1: sodium carbonate / water; methanol / 2.5 h / |Reflux
4.1: zinc; hydrogenchloride / water / 3 h / 100 °C
View Scheme
参考文献
Lyall, Catherine L.; Uosis-Martin, Mario; Lowe, John P.; Mahon, Mary F.; Pantos, G. Dan; Lewis, Simon E.
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 9 p. 1468 - 1475
Crandall, Jack K.; Magaha, H. Steve; Henderson, Mark A.; Widener, Rexford K.; Tharp, Gregg A.
Journal of Organic Chemistry, 1982 , vol. 47, # 27 p. 5372 - 5380
1.1: ozone / acetonitrile; dichloromethane / 1.5 h / -10 °C
1.2: 1 h / 20 °C
2.1: sodium carbonate / water; methanol / 2.5 h / |Reflux
3.1: zinc; hydrogenchloride / water / 3 h / 100 °C
View Scheme
参考文献
Lyall, Catherine L.; Uosis-Martin, Mario; Lowe, John P.; Mahon, Mary F.; Pantos, G. Dan; Lewis, Simon E.
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 9 p. 1468 - 1475
1: sodium carbonate / water; methanol / 2.5 h / |Reflux
2: zinc; hydrogenchloride / water / 3 h / 100 °C
View Scheme
参考文献
Lyall, Catherine L.; Uosis-Martin, Mario; Lowe, John P.; Mahon, Mary F.; Pantos, G. Dan; Lewis, Simon E.
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 9 p. 1468 - 1475
