2-甲-4-戊烯-2-醇合成路线 （共 65 条）
反应条件
in neat (no solvent) byproducts: acetone, water; 20°C, 6 h (distn. off of ketone); distn. (reduced pressure);
参考文献
Tagliavini et al.
Inorganica Chimica Acta, 1978 , vol. 26, p. L41
反应条件
N-ethyl-N,N-diisopropylamine T=0°C; 8 h;
参考文献
Walba; Thurmes; Haltiwanger
Journal of Organic Chemistry, 1988 , vol. 53, # 5 p. 1046 - 1056
反应条件
I(sym-coll)2ClO4 in dichloromethane T=20°C; 1.5 h;
参考文献
Evans, Robert D.; Magee, Joseph W.; Schauble, J. Herman
Synthesis, 1988 , # 11 p. 862 - 868
反应条件
copper; tin(ll) chloride in water
T=20°C; 3 h;
参考文献
Tan, Xiang-Hui; Shen, Bo; Liu, Lei; Guo, Qing-Xiang
Tetrahedron Letters, 2002 , vol. 43, # 51 p. 9373 - 9376
反应条件
copper; tin(ll) chloride in water
T=20°C; 3 h;
参考文献
Tan, Xiang-Hui; Shen, Bo; Liu, Lei; Guo, Qing-Xiang
Tetrahedron Letters, 2002 , vol. 43, # 51 p. 9373 - 9376
反应条件
in diethyl ether
T=0°C; Barbier-Grignard reaction; 1.5 h; Inert atmosphereReflux;
参考文献
Emmerling, Sebastian G. J.; Langer, Laura B. N.; Pihan, Sascha A.; Lellig, Philipp; Gutmann, Jochen S.
Macromolecules, 2010 , vol. 43, # 11 p. 5033 - 5042
反应条件
in tetrahydrofuran
T=0 - 20°C; 1.25 h;
参考文献
Taillier, Catherine; Hameury, Thomas; Bellosta, Veronique; Cossy, Janine
Tetrahedron, 2007 , vol. 63, # 21 p. 4472 - 4490
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; tetra-n-butylammonium perchlorate
T=0°C; current density = 25 mA/cm2, 2.0 F/mol of halide;
参考文献
Satoh; Suginome; Tokuda
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1791 - 1794
反应条件
water; oxygen
T=20°C; 24 h;
参考文献
Rodrigues, Catarina A.B.; De Matos, Marta Norton; Guerreiro, Bruno M.H.; Goncalves, Ana M.L.; Romao, Carlos C.; Afonso, Carlos A.M.
Tetrahedron Letters, 2011 , vol. 52, # 22 p. 2803 - 2807
反应条件
1: LiAlH4 / diethyl ether; tetrahydrofuran
2: (i) aq. H2O2, MeOH, (ii) (heating)
View Scheme
参考文献
Sucrow,W. et al.
Chemische Berichte, 1972 , vol. 105, p. 1621 - 1633
