甘露糖酸-delta-内酰胺合成路线 （共 23 条）
反应条件
1: 81 percent / PdCl2(PPh3)2 / ethanol / 32 h / 60 °C / 45600 Torr 2: 76 percent / NaHCO3; Oxone / acetone; H2O / 3 h / 20 °C 3: 95 percent / DBU / CH2Cl2 / 3 h / Heating 4: 43 percent / NMO; osmiun tetroxide / 2-methyl-propan-2-ol; H2O / 3 h / 20 °C 5: 70 percent / TFA / H2O / 10 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 59, # 3 p. 281 - 286
反应条件
1: 95 percent / DBU / CH2Cl2 / 3 h / Heating 2: 43 percent / NMO; osmiun tetroxide / 2-methyl-propan-2-ol; H2O / 3 h / 20 °C 3: 70 percent / TFA / H2O / 10 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 59, # 3 p. 281 - 286
反应条件
1: 7.23 g / potassium tert-butoxide / tetrahydrofuran / 3 h / 20 °C 2: 81 percent / PdCl2(PPh3)2 / ethanol / 32 h / 60 °C / 45600 Torr 3: 76 percent / NaHCO3; Oxone / acetone; H2O / 3 h / 20 °C 4: 95 percent / DBU / CH2Cl2 / 3 h / Heating 5: 43 percent / NMO; osmiun tetroxide / 2-methyl-propan-2-ol; H2O / 3 h / 20 °C 6: 70 percent / TFA / H2O / 10 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 59, # 3 p. 281 - 286
