1: 2-(3,4-dihydroxyphenyl)ethylamine hydrochloride With Na2B4O7; sodium hydrogencarbonate in water
Inert atmosphere;
2: methacrylic anhydride With sodium hydroxide in tetrahydrofuran; water
T=20°C; pH=8-9; 17 h;
参考文献
White, Evan M.; Seppala, Jonathan E.; Rushworth, Parker M.; Ritchie, Branson W.; Sharma, Suraj; Locklin, Jason
Macromolecules, 2013 , vol. 46, # 22 p. 8882 - 8887
1: 2-(3,4-dihydroxyphenyl)ethylamine hydrochloride With Na2B4O7; sodium carbonate in water
pH=> 9.5; Inert atmosphere;
2: 2-methyl-acryloyl chloride With sodium carbonate in water
T=20°C; pH=Ca. 9.8; Inert atmosphereCooling with ice;
3: With hydrogenchloride in water
pH=1 - 2;
参考文献
Ham, Hyun Ok; Liu, Zhongqiang; Lau, K. H. Aaron; Lee, Haeshin; Messersmith, Phillip B.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 3 p. 732 - 736
Fe(OH)(2+); potassium nitrate in water
T=25°C; pH=1.4; effect of pH, chloride ion, bromide ion and ionic strength on anaerobic oxidation; different reagent; Rate constantEquilibrium constantMechanism;
参考文献
El-Ayaan, Usama; Herlinger, Erwin; Jameson, Reginald F.; Linert, Wolfgang
Journal of the Chemical Society - Dalton Transactions, 1997 , # 16 p. 2813 - 2818