4,4-二甲基-2-戊醇合成路线 (共 17 条)
反应条件
lithium aluminium tetrahydride; 2,5-di-C-benzyl-1,3:4,6-di-O-benzylidene-D-mannitol in diethyl ether 2 h; Heating;
参考文献
Baggett, Neil; Simmonds, Richard J.; Stribblehill, Peter
Carbohydrate Research, 1987 , vol. 162, p. 153 - 158
参考文献
Journal of the American Chemical Society, , vol. 55, p. 4195,4558
参考文献
Journal of the American Chemical Society, , vol. 60, p. 2462,2791
反应条件
methanol; sodium hydroxide; dihydrogen peroxide; (-)-Monoisopinocampheylborane 1.) THF, -25 deg C, 48 h, 2.) 55 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 47, # 26 p. 5074 - 5083
反应条件
bis(acetylacetonate)oxovanadium; dihydrogen peroxide in acetic acid T=30°C; Product distribution;
参考文献
Doklady Chemistry, , vol. 378, # 4-6 p. 150 - 153
反应条件
perchloric acid; sodium nitrite in water Product distribution;
参考文献
Chemische Berichte, , vol. 113, # 1 p. 104 - 128
参考文献
Journal of the American Chemical Society, , vol. 55, p. 4195,4558
反应条件
sodium nitrite in perchloric acid; water 36 h; Product distributionMechanism;
参考文献
Chemische Berichte, , vol. 113, # 6 p. 2127 - 2139
反应条件
lithium aluminium tetrahydride; oxygen multistep reaction: 1) 85 deg C, 101,3 kPa, 67 h; Product distribution;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 324, # 1 p. 125 - 141
反应条件
sulfuric acid bei der Destillation;
参考文献
Whitmore; Homeyer
Journal of the American Chemical Society, 1933 , vol. 55, p. 4195,4558