2-甲氧基-5-甲基-1,4-苯醌合成路线 （共 45 条）
反应条件
oxygen; copper dichloride
T=60°C; 20 h;
参考文献
Takizawa, Yasuomi; Iwasa, Yoshihito; Suzuki, Toshiaki; Miyaji, Hiroyuki
Chemistry Letters, 1993 , # 11 p. 1863 - 1864
反应条件
trimethylsilyl trifluoromethanesulfonate in ethyl acetate
T=-23°C;
参考文献
Collins, Jon L.; Grieco, Paul A.; Walker, John K.
Tetrahedron Letters, 1997 , vol. 38, # 8 p. 1321 - 1324
反应条件
boron trifluoride diethyl etherate in dichloromethane
T=-40 - -20°C; 1 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Buechi, George; Chu, Ping-Sun
Tetrahedron, 1981 , vol. 37, # 25 p. 4509 - 4514
反应条件
poly(4-vinylpyridine-N-oxide) 2 percent cross-linked; dihydrogen peroxide; methyltrioxorhenium (VII) in ethanol; water
T=40°C;
参考文献
Saladino, Raffaele; Neri, Veronica; Mincione, Enrico; Filippone, Paolino
Tetrahedron, 2002 , vol. 58, # 42 p. 8493 - 8500
反应条件
hydrogen; palladium on activated charcoal in ethanol
参考文献
Hardegger,E. et al.
Helvetica Chimica Acta, 1964 , vol. 47, p. 1996 - 2017
反应条件
1: H2, AcOH / 10percent Pd/C / ethyl acetate / 760 Torr
2: 4.13 g / Fremy's salt, NaH2PO4 / H2O; acetone / 0.5 h
View Scheme
参考文献
Burke, John M.; Stevenson, Robert
Journal of Chemical Research, Miniprint, 1985 , # 2 p. 451 - 466
反应条件
1: FeCl3
2: H2SO4
View Scheme
参考文献
Woodward et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4223,4243
参考文献
Woodward et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4223,4243
反应条件
tin(IV) chloride in nitromethane; dichloromethane
T=-20°C; 0.166667 h; Title compound not separated from byproducts;
参考文献
Buechi, George; Chu, Ping-Sun
Tetrahedron, 1981 , vol. 37, # 25 p. 4509 - 4514
反应条件
1.1: MnO2 / diethyl ether / 18 h / 18 - 25 °C
1.2: 90 percent / aq. HCl / tetrahydrofuran / 0.5 h / 20 - 30 °C
2.1: 68 percent / potassium nitrosodisulfonate / aq. phosphate buffer; diethyl ether / 18 h
View Scheme
参考文献
Van Der Klei, Anita; De Jong, Robertus L. P.; Lugtenburg, Johan; Tielens, Aloysius G. M.
European Journal of Organic Chemistry, 2002 , # 17 p. 3015 - 3023
