(E)-11-十六碳烯-1-醇合成路线 （共 15 条）
反应条件
1: 1) Mg, 2) Li2CuCl4 / 1) THF, 2) THF, a) -70 deg C to 20 deg C over 45 min, b) 2 h at 20 deg C 2: 92 percent / TsOH*Py / methanol / 3 h / 45 °C View Scheme
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 39, # 11 p. 2296 - 2300
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 11 p. 2539 - 2544
反应条件
1: 1) BuLi / 1) HMPA, THF, hexane, 1 h, -50 deg C, 2) 30 min at -50 deg C, 1 h at 20 deg C 2: 61 percent / Li/NH3 / tetrahydrofuran / 1 h / -60 °C View Scheme
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 39, # 11 p. 2296 - 2300
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 11 p. 2539 - 2544
反应条件
sodium hydride; dimethyl sulfoxide in tetrahydrofuran 0.5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Agricultural and Biological Chemistry, , vol. 44, # 2 p. 257 - 261
反应条件
oxalyl dichloride; dimethyl sulfoxide in dichloromethane
T=-60°C; 0.25 h;
参考文献
Brown, Herbert C.; Lee, Hsiupu D.; Kulkarni, Surendra U.
Journal of Organic Chemistry, 1986 , vol. 51, # 26 p. 5282 - 5286
参考文献
Zarbin, Paulo H. G.; Lorini, Lisete M.; Ambrogi, Bianca G.; Vidal, Diogo M.; Lima, Eraldo R.
Journal of Chemical Ecology, 2007 , vol. 33, # 3 p. 555 - 565
