rel-2alpha-丙基-3alpha-甲基环氧乙烷合成路线 （共 15 条）
反应条件
n-butyllithium; potassium tert-butylate; diisopropylamine in tetrahydrofuran T=-50°C; 20 h;
参考文献
Mordini, Alessandro; Rayana, Ezzedine Ben; Margot, Christian; Schlosser, Manfred
Tetrahedron, 1990 , vol. 46, # 7 p. 2401 - 2410
反应条件
lithium aluminium tetrahydride; aluminium trichloride in diethyl ether T=35°C; 0.25 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Andrejevic, Vladimir; Bjelakovic, Mira; Mihailovic, Milan M.; Mihailovic, Mihailo Lj.
Helvetica Chimica Acta, 1985 , vol. 68, p. 2030 - 2032
反应条件
iodine; triphenylphosphine in acetonitrile T=70 - 80°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Gazzetta Chimica Italiana, , vol. 117, # 5 p. 251 - 254
反应条件
dirhodium tetraacetate in benzene-d6 0.75 h; Heating;
参考文献
Martin, Michael G.; Ganem, Bruce
Tetrahedron Letters, 1984 , vol. 25, # 3 p. 251 - 254
反应条件
lithium aluminium tetrahydride; aluminium trichloride in diethyl ether T=35°C; 0.25 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Andrejevic, Vladimir; Bjelakovic, Mira; Mihailovic, Milan M.; Mihailovic, Mihailo Lj.
Helvetica Chimica Acta, 1985 , vol. 68, p. 2030 - 2032
反应条件
water; dihydrogen peroxide; dmtacn Mn complex immobilized on amorphous SiO2 in acetonitrile
T=-0.15°C; Oxidation; 1 h; Further byproducts given;
参考文献
De Vos, Dirk E.; De Wildeman, Stefaan; Sels, Bert F.; Grobet, Piet J.; Jacobs, Pierre A.
Angewandte Chemie - International Edition, 1999 , vol. 38, # 7 p. 980 - 983
反应条件
dihydrogen peroxide; dmtacn Mn complex immobilized on amorphous SiO2 in acetonitrile
T=-0.15°C; Oxidation; 2 h; Further byproducts given;
参考文献
De Vos, Dirk E.; De Wildeman, Stefaan; Sels, Bert F.; Grobet, Piet J.; Jacobs, Pierre A.
Angewandte Chemie - International Edition, 1999 , vol. 38, # 7 p. 980 - 983
反应条件
glyoxylic acid methylester methylhemiacetal; trans-oxalate; dihydrogen peroxide; [Mn2O3(1,4,7-trimethyl-1,4,7-triazacyclononane)2](PF6)2 in acetonitrile
T=0°C;
参考文献
Brinksma, Jelle; Schmieder, Lizette; Van Vliet, Gerbert; Boaron, Rob; Hage, Ronald; De Vos, Dirk E; Alsters, Paul L; Feringa, Ben L
Tetrahedron Letters, 2002 , vol. 43, # 14 p. 2619 - 2622
反应条件
dihydrogen peroxide; Ti-MWW in acetonitrile
T=59.84°C; 2 h; Product distribution; Further Variations:CatalystsSolventsTime;
参考文献
Wu; Tatsumi
Chemical Communications, 2001 , # 10 p. 897 - 898
反应条件
oxygen; Titanium(IV) oxide in acetonitrile
P=760.051 Torr; 12 h; Irradiation; Product distribution; Further Variations:Catalysts;
参考文献
Shiraishi, Yasuhiro; Morishita, Masatsugu; Hirai, Takayuku
Chemical Communications, 2005 , # 48 p. 5977 - 5979
