顺式-1,2-二羟甲基乙烯合成路线 （共 151 条）
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; sodium hydride 1.) THF, reflux, 2 h, 2.) THF, reflux, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Ghosh, Subrata; Raychaudhuri, Swadesh R.; Salomon, Robert G.
Journal of Organic Chemistry, 1987 , vol. 52, # 1 p. 83 - 90
反应条件
NaH; tetra-(n-butyl)ammonium iodide in tetrahydrofuran; diethyl ether; hexane; water
参考文献
Abbott Laboratories
Patent: US5703244 A1, 1997 ;
反应条件
tetra-(n-butyl)ammonium iodide; sodium hydride 1.) THF, RT, 30 min, 2.) THF, RT, 15 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Chong, J. Michael; Wong, Susanna
Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2596 - 2598
反应条件
sodium hydride in tetrahydrofuran 1.) RT, 1.5 h; 2.) reflux, 20 h; 3.) RT, 10 h;
参考文献
Yuan, Wei; Berman, Richard J.; Gelb, Michael H.
Journal of the American Chemical Society, 1987 , vol. 109, # 26 p. 8071 - 8081
反应条件
C36H81Cl3P3Ru T=180°C; Yield given. Yields of byproduct given;
参考文献
Tsuji, Yasushi; Yokoyama, Yasuharu; Huh, Keun-Tae; Watanabe, Yoshihisa
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3456 - 3458
反应条件
C36H81Cl3P3Ru T=180°C; Yield given. Yields of byproduct given;
参考文献
Tsuji, Yasushi; Yokoyama, Yasuharu; Huh, Keun-Tae; Watanabe, Yoshihisa
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3456 - 3458
反应条件
hydrogen; montmorillonite-diphenylphosphinepalladium(II) P=760 Torr; 30 h; Ambient temperature;
参考文献
Chickos, James S.; Uang, Jack Y.-J.; Keiderling, Tim A.
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2594 - 2596
反应条件
hydrogen; Montmorillonite-Ph2PPd(II) in tetrahydrofuran T=25°C; P=760 Torr; 2 h; other catalysts (Lindlar catalyst); no solvent; at 50 deg C; Product distribution;
参考文献
Chickos, James S.; Uang, Jack Y.-J.; Keiderling, Tim A.
Journal of Organic Chemistry, 1991 , vol. 56, # 7 p. 2594 - 2596
反应条件
C36H81Cl3P3Ru T=180°C; Yield given. Yields of byproduct given;
参考文献
Tsuji, Yasushi; Yokoyama, Yasuharu; Huh, Keun-Tae; Watanabe, Yoshihisa
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3456 - 3458
反应条件
C55H58ClN3ORu; phenyl-trichloro-silane in toluene T=50°C; 5 h;
参考文献
Behr, Arno; Gomes, Jessica Perez
Beilstein Journal of Organic Chemistry, 2011 , vol. 7, p. 1 - 8
