N,N-二甲基苯甲酰胺合成路线 （共 319 条）
反应条件
sodium perchlorate in water; acetonitrile
controlled-potential electrolysis; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Hall, Larry R.; Iwamoto, Reynold T.; Hanzlik, Robert P.
Journal of Organic Chemistry, 1989 , vol. 54, # 10 p. 2446 - 2451
反应条件
N,N-diisopropylpicolinamide; lithium diisopropyl amide in diethyl ether; benzene
-78 deg C, 2 h; 25 deg C, 1.5 h;
参考文献
Epsztajn, Jan; Brzezinski, Jacek Z.; Jozwiak, Andrzej
Journal of Chemical Research, Miniprint, 1986 , # 1 p. 401 - 441
反应条件
lithium diisopropyl amide
1.) Et2O, 0.25h, 2.) MeOH, 0.75h; Yield given. Multistep reaction;
参考文献
Epsztajn, J.; Brzezinski, J. Z.; Czeh, K.
Monatshefte fuer Chemie, 1993 , vol. 124, # 5 p. 549 - 558
反应条件
lithium diisopropyl amide
1.) Et2O, C6H6, -78 deg C, 1 h, 2.) -78 deg C, 2 h; 25 deg C, 1.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Epsztajn, Jan; Brzezinski, Jacek Z.; Jozwiak, Andrzej
Journal of Chemical Research, Miniprint, 1986 , # 1 p. 401 - 441
反应条件
1: N,N-Diisopropyl-3-pyridinecarboxamide With lithium diisopropyl amide in tetrahydrofuran; n-heptane; ethylbenzene
T=-80°C; 0.25 h;
2: N,N-dimethyl benzamide in tetrahydrofuran; n-heptane; ethylbenzene
T=-80 - 20°C; 3 h;
参考文献
Broussy, Sylvain; Bernardes-Genisson, Vania; Gornitzka, Heinz; Bernadou, Jean; Meunier, Bernard
Organic and Biomolecular Chemistry, 2005 , vol. 3, # 4 p. 666 - 669
反应条件
lithium diisopropyl amide
1.) Et2O, C6H6, -78 deg C, 1 h, 2.) -78 deg C, 2 h; 25 deg C, 1.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Epsztajn, Jan; Brzezinski, Jacek Z.; Jozwiak, Andrzej
Journal of Chemical Research, Miniprint, 1986 , # 1 p. 401 - 441
反应条件
lithium diisopropyl amide
1.) Et2O, 0.25h, 2.) MeOH, 0.75h; Yield given. Multistep reaction;
参考文献
Epsztajn, J.; Brzezinski, J. Z.; Czeh, K.
Monatshefte fuer Chemie, 1993 , vol. 124, # 5 p. 549 - 558
反应条件
lithium diisopropyl amide
1.) Et2O, C6H6, -78 deg C, 1 h, 2.) -78 deg C, 2 h; 25 deg C, 1.5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Epsztajn, Jan; Brzezinski, Jacek Z.; Jozwiak, Andrzej
Journal of Chemical Research, Miniprint, 1986 , # 1 p. 401 - 441
反应条件
methanol-d1; lithium diisopropyl amide
1.) Et2O, -78 deg C, 0.25h, 2.) MeOH, 0.75h, different temperature, reaction time, amount of base; Product distribution;
参考文献
Epsztajn, Jan; Bieniek, Adam; Brzezinski, Jacek Z.; Jozwiak, Andrzej
Tetrahedron Letters, 1983 , vol. 24, # 43 p. 4735 - 4738
反应条件
1: COCl2 / toluene
2: (i) Et2O, (ii) H2O
View Scheme
参考文献
Eilingsfeld,H. et al.
Chemische Berichte, 1963 , vol. 96, p. 2671 - 2690
