thionyl chloride in benzene 0.5 h; Heating;

1: 1.) 6 N HCl, NaNO2; 2.) CuCl2 / 1.) H2O, -5 deg C, 1 h; 2.) H2O, 50-55 deg C 2: 89 percent / conc. H2SO4 / 7 h / Heating 3: 83 percent / hydrogen / 10percent Pd-C / acetic acid / Ambient temperature 4: 1.) 6 N HCl, NaNO2; 2.) NaN3 / 1.) -5 deg C, 1 h; 2.) H2O, r.t. 5: 70 percent / o-dichlorobenzene / 1 h / 160 - 170 °C 6: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 7: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

1: 89 percent / conc. H2SO4 / 7 h / Heating 2: 83 percent / hydrogen / 10percent Pd-C / acetic acid / Ambient temperature 3: 1.) 6 N HCl, NaNO2; 2.) NaN3 / 1.) -5 deg C, 1 h; 2.) H2O, r.t. 4: 70 percent / o-dichlorobenzene / 1 h / 160 - 170 °C 5: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 6: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

1: 83 percent / hydrogen / 10percent Pd-C / acetic acid / Ambient temperature 2: 1.) 6 N HCl, NaNO2; 2.) NaN3 / 1.) -5 deg C, 1 h; 2.) H2O, r.t. 3: 70 percent / o-dichlorobenzene / 1 h / 160 - 170 °C 4: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 5: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

1: 1.) 6 N HCl, NaNO2; 2.) CuCl2 / 1.) H2O, -5 deg C, 1 h; 2.) H2O, 50-55 deg C 2: 89 percent / conc. H2SO4 / 7 h / Heating 3: 83 percent / hydrogen / 10percent Pd-C / acetic acid / Ambient temperature 4: 1.) 6 N HCl, NaNO2; 2.) NaN3 / 1.) -5 deg C, 1 h; 2.) H2O, r.t. 5: 70 percent / o-dichlorobenzene / 1 h / 160 - 170 °C 6: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 7: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

暂无反应条件数据

1: 1.) 6 N HCl, NaNO2; 2.) NaN3 / 1.) -5 deg C, 1 h; 2.) H2O, r.t. 2: 70 percent / o-dichlorobenzene / 1 h / 160 - 170 °C 3: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 4: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

1: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 2: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

1: 70 percent / o-dichlorobenzene / 1 h / 160 - 170 °C 2: 90 percent / 10percent aq. NaOH / ethanol / 1 h / Heating 3: 87 percent / SOCl2 / benzene / 0.5 h / Heating View Scheme

in dichloromethane; acetone 0.5 h; Ambient temperature;