1-(二氯甲基)-2-甲基苯合成路线 （共 16 条）
反应条件
1: 80 percent / 541 °C / 0.08 Torr 2: 1.) Mg / 1.) THF View Scheme
参考文献
Schiess, Peter; Rutschmann, Suzanne; Toan, Van Vien
Tetrahedron Letters, 1982 , vol. 23, # 36 p. 3669 - 3672
参考文献
Chemical Communications, , # 13 p. 1163 - 1164
反应条件
T=541°C; P=0.08 Torr; Yields of byproduct given;
参考文献
Schiess, Peter; Rutschmann, Suzanne; Toan, Van Vien
Tetrahedron Letters, 1982 , vol. 23, # 36 p. 3669 - 3672
参考文献
Aitken, R. Alan; Hodgson, Philip K. G.; Oyewale, Adebayo O.; Morrison, John J.
Chemical Communications, 1997 , # 13 p. 1163 - 1164
参考文献
Monsanto Company
Patent: US4593144 A1, 1986 ;
反应条件
T=541°C; P=0.08 Torr; Yields of byproduct given;
参考文献
Schiess, Peter; Rutschmann, Suzanne; Toan, Van Vien
Tetrahedron Letters, 1982 , vol. 23, # 36 p. 3669 - 3672
反应条件
tetrachloromethane; nickel; copper in N,N-dimethyl-formamide
T=60°C; Chlorination; 5 h;
参考文献
Leonel, Eric; Paugam, Jean-Paul; Heintz, Monique; Nedelec, Jean-Yves
Synthetic Communications, 1999 , vol. 29, # 22 p. 4015 - 4024
反应条件
hydrogenchloride; calcium hydroxide powder; triphenylphosphine; palladium in water; dichloro bis(triphenylphosphine)palladium (II); tert-butyl alcohol
参考文献
Sagami Chemical Research Center; Iharanikkei Chemical Industry Co., Ltd
Patent: US5886211 A1, 1999 ;
反应条件
2,2'-azo-bisisobutyronitrile; chlorine
T=90°C; 4 h;
参考文献
Showa Denko K.K.
Patent: US6372921 B1, 2002 ;
Location in patent: Example 14 ;
反应条件
in dichloromethane
T=20°C; 168 h; Sealed tube;
参考文献
Dolci, Sara; Marchetti, Fabio; Pampaloni, Guido; Zacchini, Stefano
Dalton Transactions, 2013 , vol. 42, # 16 p. 5635 - 5648
