2,4-二羟基-1,3,5-三甲基苯合成路线 （共 14 条）
反应条件
1: H2O / diethyl ether
2: aq. HCl / Heating
View Scheme
参考文献
Barton,D.H.R.; Quinkert,G.
Journal of the Chemical Society, 1960 , p. 1 - 9
反应条件
1: aq. NH3, H2S / ethanol / Heating
2: (i) aq. H2SO4, NaNO2, (ii) (heating)
3: (i) Sn, aq. HCl, (ii) NaNO2, aq. H2SO4, (iii) (heating)
View Scheme
参考文献
Stein,A.R.
Canadian Journal of Chemistry, 1965 , vol. 43, p. 1493 - 1507
反应条件
1: HNO3
2: aq. NH3, H2S / ethanol / Heating
3: (i) aq. H2SO4, NaNO2, (ii) (heating)
4: (i) Sn, aq. HCl, (ii) NaNO2, aq. H2SO4, (iii) (heating)
View Scheme
参考文献
Stein,A.R.
Canadian Journal of Chemistry, 1965 , vol. 43, p. 1493 - 1507
反应条件
sodium methylate
T=220°C;
参考文献
Cornforth; Cornforth; Robinson
Journal of the Chemical Society, 1942 , p. 682,684
Journal of the Chemical Society, 1943 , p. 168
反应条件
sodium methylate
T=220°C;
参考文献
Cornforth; Cornforth; Robinson
Journal of the Chemical Society, 1942 , p. 682,684
Journal of the Chemical Society, 1943 , p. 168
反应条件
amalgamated zinc; ethanol; acetic acid
Reagens 4: wss. HCl;
参考文献
Bauer-Benedikt; Punzengruber
Monatshefte fuer Chemie, 1950 , vol. 81, p. 772,776
反应条件
amalgamated zinc; ethanol; acetic acid
Reagens 4: wss. HCl;
参考文献
Bauer-Benedikt; Punzengruber
Monatshefte fuer Chemie, 1950 , vol. 81, p. 772,776
反应条件
1: HCl; diethyl ether / beim Erhitzen des Reaktionsprodukts mit H2O
2: ethanol; acetic acid; amalgamated zinc / Reagens 4: wss. HCl
View Scheme
参考文献
Bauer-Benedikt; Punzengruber
Monatshefte fuer Chemie, 1950 , vol. 81, p. 772,776
反应条件
hydrogenchloride
Heating;
参考文献
Barton,D.H.R.; Quinkert,G.
Journal of the Chemical Society, 1960 , p. 1 - 9
反应条件
(i) Sn, aq. HCl, (ii) NaNO2, aq. H2SO4, (iii) (heating); Multistep reaction;
参考文献
Stein,A.R.
Canadian Journal of Chemistry, 1965 , vol. 43, p. 1493 - 1507
