1,1-二甲基-2,3-二(亚甲基)环己烷合成路线 （共 12 条）
反应条件
3-chloro-benzenecarboperoxoic acid in diethyl ether 72 h; Ambient temperature;
参考文献
Serramedan
Tetrahedron Letters, 1992 , vol. 33, # 31 p. 4457 - 4460
反应条件
1: 70 percent / MCPBA / diethyl ether / 72 h / Ambient temperature 2: p-toluenesulfonic acid / benzene / 3 h / Heating View Scheme
参考文献
Serramedan
Tetrahedron Letters, 1992 , vol. 33, # 31 p. 4457 - 4460
反应条件
1: 45 percent / O2; tetraphenylporphyrine / CCl4 / 7 h / -15 °C 2: triphenylphosphine / cyclohexane / 1 h / Heating View Scheme
参考文献
Quirin, Marie Jeanne; Taran, Martine; Delmond, Bernard
Canadian Journal of Chemistry, 1996 , vol. 74, # 10 p. 1852 - 1856
反应条件
1: 70 percent / MCPBA / diethyl ether / 72 h / Ambient temperature 2: 1.) PTSA / 1.) benzene, reflux, 3 h; 2.) benzene, hexane, r.t., 12 h then reflux, 4 h 3: LiCl / dimethylsulfoxide; H2O / 1 h / 180 °C View Scheme
参考文献
Marc; Soulet; Serramedan; Delmond
Tetrahedron, 1994 , vol. 50, # 11 p. 3381 - 3388
反应条件
1: 70 percent / MCPBA / diethyl ether / 72 h / Ambient temperature 2: 1.) PTSA / 1.) benzene, reflux, 3 h; 2.) benzene, hexane, r.t., 12 h then reflux, 4 h 3: LiCl / dimethylsulfoxide; H2O / 1 h / 180 °C View Scheme
参考文献
Marc; Soulet; Serramedan; Delmond
Tetrahedron, 1994 , vol. 50, # 11 p. 3381 - 3388
参考文献
Ohloff
Justus Liebigs Annalen der Chemie, 1959 , vol. 627, p. 79,91
反应条件
N-phenyl-N-β-naphthylamine
T=140°C;
参考文献
Ohloff
Justus Liebigs Annalen der Chemie, 1959 , vol. 627, p. 79,91
反应条件
1: 1) 9-BBN, 2) 30percent H2O2, 6N NaOH / 1) THF, 6 h, reflux, 2) THF, EtOH, 50 deg C, 1 h
2: pyridinium chlorochromate / CH2Cl2 / 0.75 h / Ambient temperature
View Scheme
参考文献
Serramedan
Tetrahedron Letters, 1992 , vol. 33, # 31 p. 4457 - 4460
反应条件
hydrogen bromide; copper(I) bromide
20 h;
参考文献
Quirin, Marie Jeanne; Taran, Martine; Delmond, Bernard
Canadian Journal of Chemistry, 1996 , vol. 74, # 10 p. 1852 - 1856
反应条件
hydrogen bromide; copper(I) bromide
2 h; Yields of byproduct given;
参考文献
Quirin, Marie Jeanne; Taran, Martine; Delmond, Bernard
Canadian Journal of Chemistry, 1996 , vol. 74, # 10 p. 1852 - 1856
