tetrachlorosilane; silver perchlorate; [3H]-Caproic acid in dichloromethane 24 h; Ambient temperature;

1.1: potassium fluoride; tris(4-methoxyphenyl)-phosphine; tetrakis-(ethylene)-μ,μ'-dichlorodirhodium(I) / 1-methyl-pyrrolidin-2-one / 16 h / 200 °C / |Inert atmosphere; |Glovebox 2.1: potassium hydroxide / 1-methyl-pyrrolidin-2-one; water / 1 h / 100 °C / |Inert atmosphere 2.2: 16.17 h / 70 - 170 °C / |Inert atmosphere View Scheme

1: potassium fluoride; tris(4-methoxyphenyl)-phosphine; tetrakis-(ethylene)-μ,μ'-dichlorodirhodium(I) / 1-methyl-pyrrolidin-2-one / 16 h / 200 °C / |Inert atmosphere; |Glovebox 2: potassium carbonate / 1-methyl-pyrrolidin-2-one / 3 h / 55 °C / |Inert atmosphere View Scheme

[Pd(.eta.(5)-C5H5)Fe(.eta.(5)-C5H3-C(CH3)=N-C6H4-4-CH3)Cl(P(C6H5)3)]; potassium carbonate in 1,4-dioxane T=110°C; 12 h; Inert atmosphere;

tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran Negishi-type cross-coupling; Heating;

phosphorus pentachloride; trichlorophosphate

1: POCl3; PCl5 View Scheme

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