反应条件
1: With dicarbonylacetylacetonato rhodium (I); 2-isopropoxy-1-methyl-3-phenyl-2,3-dihydro-1H-benzo[d][1,3]azaphosphole; hydrogen; toluene-4-sulfonic acid in benzene
T=45°C; hydroformylation; P=10343.2 Torr; 16 h;
2: With sodium acetate; pyridinium chlorochromate in dichloromethane
12 h; Molecular sieve; MechanismReactivity; Reagent/catalystConcentration; optical yield given as percent deregioselective reaction;
参考文献
Lightburn, Thomas E.; Dombrowski, Michael T.; Tan, Kian L.
Journal of the American Chemical Society, 2008 , vol. 130, # 29 p. 9210 - 9211
