(Z)-[(9-十八烯氧)甲基]环氧乙烷合成路线 （共 5 条）
反应条件
sodium hydroxide; sodium acetate
参考文献
Kao Corporation
Patent: US5932755 A1, 1999 ;
反应条件
1: (Z)-9-Octadecen-1-ol With sodium hydride in tetrahydrofuran; mineral oil
T=20°C; 0.5 h; Inert atmosphere;
2: epichlorohydrin in tetrahydrofuran; mineral oil
Inert atmosphereReflux;
参考文献
UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INC.; SVETLOV, Stanislav; VAKULENKO, Anatoliy
Patent: WO2010/17550 A2, 2010 ;
Location in patent: Page/Page column 33 ;
反应条件
BF3.OEt2 in dichloromethane
参考文献
Atairgin Technologies, Inc.
Patent: US6380177 B1, 2002 ;
US 6380177 B1
反应条件
sodium hydroxide in methanol; water
16 h;
参考文献
Goddard, John G.; Picker, Donald H.; Umansky, Samull R.; Price, Steven; Wijkmans, Jac; Boyd, Edward; Baxter, Anthony
Patent: US6949528 B1, 2005 ;
Location in patent: Page/Page column 1 ;
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; sodium hydride
1.) THF, reflux, 2 h, 2.) THF, reflux, 16 h; Yield given. Multistep reaction;
参考文献
Nuss, Simone; Oudet, Pierre; Mioskowski, Charles; Lebeau, Luc
Chemistry and Physics of Lipids, 1996 , vol. 84, # 1 p. 13 - 20
