2,2'-联萘基-1,1'-二醇合成路线 （共 16 条）
反应条件
tin(IV) chloride in dichloromethane T=100°C; 118 h;
参考文献
Takeya, Tetsuya; Doi, Hirohisa; Ogata, Tokutaro; Otsuka, Tsuyoshi; Okamoto, Iwao; Kotani, Eiichi
Tetrahedron, 2004 , vol. 60, # 30 p. 6295 - 6310
反应条件
boron tribromide in dichloromethane
T=-10 - 20°C; 3 h; Inert atmosphere;
参考文献
Mazzanti, Andrea; Chiarucci, Michel; Bentley, Keith W.; Wolf, Christian
Journal of Organic Chemistry, 2014 , vol. 79, # 8 p. 3725 - 3730
反应条件
tin(IV) chloride in dichloromethane
T=100°C; 121 h;
参考文献
Takeya, Tetsuya; Doi, Hirohisa; Ogata, Tokutaro; Otsuka, Tsuyoshi; Okamoto, Iwao; Kotani, Eiichi
Tetrahedron, 2004 , vol. 60, # 30 p. 6295 - 6310
反应条件
2,6-dimethylpyridine; sodium perchlorate in acetonitrile
electrolysis;
参考文献
Kashiwagi, Yoshitomo; Ono, Hiroaki; Osa, Tetsuo
Chemistry Letters, 1993 , # 1 p. 81 - 84
反应条件
1.1: n-butyllithium; N,N,N',N,-tetramethylethylenediamine / cyclohexane; hexane / 3 h / 0 - 20 °C / |Inert atmosphere
1.2: 5 h / 0 - 20 °C
2.1: bronze / neat (no solvent) / 5 h / 190 °C / |Inert atmosphere
3.1: boron tribromide / dichloromethane / 3 h / -10 - 20 °C / |Inert atmosphere
View Scheme
参考文献
Jumde, Varsha R.; Iuliano, Anna
European Journal of Organic Chemistry, 2013 , # 20 p. 4294 - 4302
反应条件
1: N-ethyl-N,N-diisopropylamine; N-bromosuccinmide / dichloromethane / 8 h / 40 °C / |Inert atmosphere
2: potassium hydroxide / acetonitrile / 12 h / 20 °C / |Inert atmosphere
3: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / water; toluene; ethanol / 12 h / 100 °C
4: boron tribromide / dichloromethane / 2 h / 20 °C
View Scheme
参考文献
Bentley, Keith W.; Nam, Yea G.; Murphy, Jaslynn M.; Wolf, Christian
Journal of the American Chemical Society, 2013 , vol. 135, # 48 p. 18052 - 18055
反应条件
1: potassium hydroxide / acetonitrile / 12 h / 20 °C / |Inert atmosphere
2: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / water; toluene; ethanol / 12 h / 100 °C
3: boron tribromide / dichloromethane / 2 h / 20 °C
View Scheme
参考文献
Bentley, Keith W.; Nam, Yea G.; Murphy, Jaslynn M.; Wolf, Christian
Journal of the American Chemical Society, 2013 , vol. 135, # 48 p. 18052 - 18055
反应条件
1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / water; toluene; ethanol / 12 h / 100 °C
2: boron tribromide / dichloromethane / 2 h / 20 °C
View Scheme
参考文献
Bentley, Keith W.; Nam, Yea G.; Murphy, Jaslynn M.; Wolf, Christian
Journal of the American Chemical Society, 2013 , vol. 135, # 48 p. 18052 - 18055
反应条件
1: tetrakis(triphenylphosphine) palladium(0); potassium phosphate / water; toluene; ethanol / 12 h / 100 °C
2: boron tribromide / dichloromethane / 2 h / 20 °C
View Scheme
参考文献
Bentley, Keith W.; Nam, Yea G.; Murphy, Jaslynn M.; Wolf, Christian
Journal of the American Chemical Society, 2013 , vol. 135, # 48 p. 18052 - 18055
反应条件
1: iron (II)-sulfate; aqueous ammonia
2: aqueous H2SO4; KI / 90 - 100 °C / Diazotization
3: copper-powder; iodine / 200 - 210 °C
4: aqueous HI
View Scheme
参考文献
Clemo; Cockburn; Spence
Journal of the Chemical Society, 1931 , p. 1265,1271
