17-乙炔基-17-羟基雌甾-1,3,5(10)-三烯-3-基吡喃己醛糖苷酸合成路线 （共 6 条）
反应条件
sodium hydroxide in methanol T=20°C; Hydrolysis; 48 h;
参考文献
Werschkun, Barbara; Gorziza, Karin; Thiem, Joachim
Journal of Carbohydrate Chemistry, 1999 , vol. 18, # 6 p. 629 - 637
反应条件
1: 66 percent / potassium carbonate / methanol / 0.5 h / 20 °C 2: 61 percent / boron trifluoride diethyl etherate / CH2Cl2 / 0.5 h / -20 °C 3: 74 percent / sodium hydroxide / methanol / 48 h / 20 °C View Scheme
参考文献
Journal of Carbohydrate Chemistry, , vol. 18, # 6 p. 629 - 637
反应条件
1: 100 percent / pyridine / 48 h / 100 °C 2: 66 percent / potassium carbonate / methanol / 0.5 h / 20 °C 3: 61 percent / boron trifluoride diethyl etherate / CH2Cl2 / 0.5 h / -20 °C 4: 74 percent / sodium hydroxide / methanol / 48 h / 20 °C View Scheme
参考文献
Journal of Carbohydrate Chemistry, , vol. 18, # 6 p. 629 - 637
反应条件
1: 61 percent / boron trifluoride diethyl etherate / CH2Cl2 / 0.5 h / -20 °C 2: 74 percent / sodium hydroxide / methanol / 48 h / 20 °C View Scheme
参考文献
Journal of Carbohydrate Chemistry, , vol. 18, # 6 p. 629 - 637
→
26011-40-5(8S,9S,13S,14S)-17-乙炔基-3-甲氧基-13-甲基-7,8,9,11,12,14,15,16-八氢-6H-环戊二烯并[a]菲-2,17-二醇+
反应条件
metabolism in women in dependence on geographic locality; Product distribution;
参考文献
Steroids, , vol. 36, # 3 p. 255 - 282
→
75803-36-0[(8R,9S,13S,14S,17R)-17-乙炔基-3-羟基-13-甲基-7,8,9,11,12,14,15,16-八氢-6H-环戊并[a]菲-17-基]氢硫酸盐+
反应条件
metabolism in women in dependence on geographic locality; Product distribution;
参考文献
Steroids, , vol. 36, # 3 p. 255 - 282
