2,6-二甲基-5,7-辛二烯-2-醇合成路线 （共 5 条）
反应条件
in diethyl ether
T=0°C; 0.5 h;
参考文献
Andersson, Pher G.; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5349 - 5353
反应条件
1: 86 percent / Et3N, DMAP / 24 h / Ambient temperature
2: 1) NaH, 2) PBu3 / 2) Pd(OAc)2 / 1) THF, oil, 2) 3 h, 40 deg C
3: 88 percent / NaCN, H2O / dimethylsulfoxide / 36 h / 80 °C
4: 91 percent / diethyl ether / 0.5 h / 0 °C
View Scheme
参考文献
Andersson, Pher G.; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5349 - 5353
反应条件
1: 1) NaH, 2) PBu3 / 2) Pd(OAc)2 / 1) THF, oil, 2) 3 h, 40 deg C
2: 88 percent / NaCN, H2O / dimethylsulfoxide / 36 h / 80 °C
3: 91 percent / diethyl ether / 0.5 h / 0 °C
View Scheme
参考文献
Andersson, Pher G.; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5349 - 5353
反应条件
1: 88 percent / NaCN, H2O / dimethylsulfoxide / 36 h / 80 °C
2: 91 percent / diethyl ether / 0.5 h / 0 °C
View Scheme
参考文献
Andersson, Pher G.; Baeckvall, Jan-E.
Journal of Organic Chemistry, 1991 , vol. 56, # 18 p. 5349 - 5353
反应条件
in water
Heatinghydrodistillation; effect of pH; Product distributionRate constant;
参考文献
Morin, Ph.; Gunther, C.; Peyron, L.; Richard, H.
Bulletin de la Societe Chimique de France, 1985 , # 5 p. 921 - 930
