hydrogen; palladium dihydroxide in ethanol
P=300.024 Torr; 48 h;
参考文献
Sattely, Elizabeth S.; Alexander Cortez; Moebius, David C.; Schrock, Richard R.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2005 , vol. 127, # 23 p. 8526 - 8533
1: With (S)-Me2Si(η5-OHF)(η5-C5H3(-)-menthyl)Smn(TMS)2 in benzene-d6
T=25°C; 168 h;
2: With sodium hydroxide; benzyl chloroformate in diethyl ether; benzene-d6
3: With hydrogen; palladium on activated charcoal in ethanol
T=20°C; 1 h; Title compound not separated from byproducts;
参考文献
Hong, Sukwon; Kawaoka, Amber M.; Marks, Tobin J.
Journal of the American Chemical Society, 2003 , vol. 125, # 51 p. 15878 - 15892
Sattely, Elizabeth S.; Alexander Cortez; Moebius, David C.; Schrock, Richard R.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2005 , vol. 127, # 23 p. 8526 - 8533
1: chiral Mo complex / benzene / 12 h / 22 °C
2: ClRh(PPh3)3; H2 / benzene / 48 h / 20685.9 Torr
3: H2 / Pd(OH)2/C / ethanol / 48 h / 300.02 Torr
View Scheme
参考文献
Sattely, Elizabeth S.; Alexander Cortez; Moebius, David C.; Schrock, Richard R.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2005 , vol. 127, # 23 p. 8526 - 8533
1: 92 percent / Na / tetrahydrofuran; liquid ammonia / 1 h / -60 °C
2: chiral Mo complex / benzene / 12 h / 22 °C
3: ClRh(PPh3)3; H2 / benzene / 48 h / 20685.9 Torr
4: H2 / Pd(OH)2/C / ethanol / 48 h / 300.02 Torr
View Scheme
参考文献
Sattely, Elizabeth S.; Alexander Cortez; Moebius, David C.; Schrock, Richard R.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2005 , vol. 127, # 23 p. 8526 - 8533
Ghislieri, Diego; Green, Anthony P.; Pontini, Marta; Willies, Simon C.; Rowles, Ian; Frank, Annika; Grogan, Gideon; Turner, Nicholas J.
Journal of the American Chemical Society, 2013 , vol. 135, # 29 p. 10863 - 10869
