tetrachloromethane; triphenylphosphine 8 h; Heating;

1: With methyl-magnesium chloride in tetrahydrofuran T=-80°C; 0.166667 h; 2: With ammonium chloride Further stages.;

1.1: 100 percent / diethyl ether; methanol / 24 h / 10 °C 2.1: O3 / CH2Cl2; methanol / -78 °C 2.2: 73 percent / Ph3P / CH2Cl2; methanol / 0.5 h 3.1: 76 percent / CH2Cl2 / 5 h / Heating 4.1: H2 / 10 percent Pd/C / ethyl acetate / 20 °C 4.2: 76 percent / LiAlH4 / tetrahydrofuran / 5 h / Heating 5.1: 78 percent / CCl4; Ph3P / 8 h / Heating View Scheme

1.1: H2 / 10 percent Pd/C / ethyl acetate / 20 °C 1.2: 76 percent / LiAlH4 / tetrahydrofuran / 5 h / Heating 2.1: 78 percent / CCl4; Ph3P / 8 h / Heating View Scheme

1.1: 76 percent / CH2Cl2 / 5 h / Heating 2.1: H2 / 10 percent Pd/C / ethyl acetate / 20 °C 2.2: 76 percent / LiAlH4 / tetrahydrofuran / 5 h / Heating 3.1: 78 percent / CCl4; Ph3P / 8 h / Heating View Scheme

1.1: N-chlorosuccinimide / CCl4 / 15 h / 20 °C 2.1: CH3MgCl / tetrahydrofuran / 0.17 h / -80 °C 2.2: 44 percent / aq. NH4Cl View Scheme

1: sodium 2: N.N-dimethyl-aniline; chloroform; SOCl2 View Scheme

in various solvent(s) T=100°C; CIDNP, thermolyse; Mechanism;

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