4-三甲硅基-3-丁炔-2-酮合成路线 （共 32 条）
反应条件
aluminium trichloride in carbon disulfide
参考文献
Bulletin de la Societe Chimique de France, , vol. 2, # 1-2 p. 7 - 13
反应条件
1: trimethylsilylacetylene With ethyl magnesium chloride in tetrahydrofuran T=0°C; 0.333333 h; 2: acetic anhydride in tetrahydrofuran Further stages.;
参考文献
Journal of Organic Chemistry, , vol. 67, # 9 p. 3149 - 3151
反应条件
Iron (III) nitrate nonahydrate; 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; sodium chloride in toluene T=20 - 55°C; 7.4 h;
参考文献
Synthesis, , vol. 44, # 10 p. 1569 - 1576
反应条件
n-butyllithium; zinc(II) chloride in tetrahydrofuran; hexane T=25°C; 0.5 h;
参考文献
Journal of Organometallic Chemistry, , vol. 338, p. 289 - 294
反应条件
sulfuric acid; water in acetone T=20°C; Hydrolysis; 2 h;
参考文献
Russian Journal of Organic Chemistry, , vol. 35, # 4 p. 608 - 613
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane T=20°C; Friedel-Crafts reaction; 1 h;
参考文献
Synlett, , # 1 p. 45 - 48
反应条件
aluminium trichloride in dichloromethane T=-20°C;
参考文献
Tetrahedron, , vol. 58, # 24 p. 4975 - 4980
反应条件
sulfuric acid in water; acetone 5 h; Heating;
参考文献
Tetrahedron, , vol. 39, # 19 p. 3073 - 3082
反应条件
1: isopropylmagnesium chloride; trimethylsilylacetylene in tetrahydrofuran T=-20 - 0°C; 2: acetic anhydride in tetrahydrofuran T=0 - 20°C; 3 h;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 9 p. 1611 - 1614
反应条件
in tetrahydrofuran acetic anhydride was added dropwise to a soln. of complex in THF at -20°C, stirred for 1 h, gradually warmed to 25°C, stirred for 2 h at 25°C; volatiles were removed in vac., the organic products were extd. with cold (-20°C) diethyl ether, the residue was dried in vac.;
参考文献
Journal of Organometallic Chemistry, , vol. 625, # 2 p. 140 - 147
