N,N'-二苯基间苯二胺合成路线 （共 16 条）
反应条件
copper(l) iodide; n-butyllithium 1.) hexane, diphenyl ether, 15 min, room temperature, 2.) 200 deg C, 48 h.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Wienk; Janssen
Journal of the American Chemical Society, 1997 , vol. 119, # 19 p. 4492 - 4501
反应条件
palladium monocarbide in cyclohexanone
参考文献
Mitsui Toatsu Chemicals, Inc.
Patent: US4804783 A1, 1989 ;
反应条件
sodium t-butanolate; Ni(0)*2IPr in 1,4-dioxane
T=100°C;
参考文献
Kuhl, Sebastien; Fort, Yves; Schneider, Raphael
Journal of Organometallic Chemistry, 2005 , vol. 690, # 24-25 p. 6169 - 6177
反应条件
1: in tetrahydrofuran
T=-20°C; 2 h;
2: With sodium tetrahydroborate; iron(II) chloride in tetrahydrofuran
T=-20 - 20°C; 2 h;
参考文献
Sapountzis, Ioannis; Knochel, Paul
Synlett, 2004 , # 6 p. 955 - 958
反应条件
1: 1,3-diamino-benzene With n-butyllithium; ZnCl2*TMEDA in tetrahydrofuran; hexane
T=0 - 20°C; 0.5 h; Inert atmosphereSchlenk technique;
2: phenyl-magnesium bromide With N,N'-dimethyl-N,N'-propyleneurea; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane in tetrahydrofuran; hexane
T=0 - 20°C; 3 h; Inert atmosphereSchlenk technique;
参考文献
Ilies, Laurean; Matsubara, Tatsuaki; Nakamura, Eiichi
Organic Letters, 2012 , vol. 14, # 21 p. 5570 - 5573,4
反应条件
1: With copper (I) iodide; potassium carbonate
Phenylation; 25 h; Heating;
2: With potassium hydroxide in ethanol
Deacetylation; 4.5 h; Heating;
参考文献
Chakrabarty; Batabyal; Khasnobis
Synthetic Communications, 2000 , vol. 30, # 20 p. 3651 - 3668
反应条件
copper(l) iodide; potassium carbonate
T=180°C; 24 h;
参考文献
Ito, Akihiro; Saito, Takeshi; Tanaka, Kazuyoshi; Yamabe, Tokio
Tetrahedron Letters, 1995 , vol. 36, # 48 p. 8809 - 8812
参考文献
Kozaki, Masatoshi; Nakamura, Shogo; Sato, Kazunobu; Takui, Takeji; Kamatani, Takeaki; Oda, Masaji; Tokumaru, Katsumi; Okada, Keiji
Tetrahedron Letters, 1998 , vol. 39, # 33 p. 5979 - 5982
反应条件
sodium; copper
1.) 180 deg C, 3 h, 2.) 230 deg C, 30 h;; Yield given. Multistep reaction;
参考文献
Shein, S. M.; Rusov, V. P.; Sokolenko, V. I.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 2014 - 2016
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 11 p. 2356 - 2358
反应条件
water
Erhitzen des Reaktionsprodukts mit wss.Natronlauge;
参考文献
I.G.Farbenind.
Patent: DE643221 , 1930 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 275,277
Full Text Show Details
Gen.Aniline Works
Patent: US2059466 , 1935 ;
