ammonium acetate

bromine; sodium acetate; acetic acid

暂无反应条件数据

1: With sodium chlorite; sodium dihydrogenphosphate; dihydrogen peroxide in water; acetonitrile T=10 - 20°C; 1.5 h; 2: With sodium thiosulfate in water; acetonitrile 0.0833333 h;

1: potassium tert-butylate / tetrahydrofuran / 0.58 h / 0 °C / |Schlenk technique 2: hydrogenchloride / tetrahydrofuran; water / 2 h / |Schlenk technique; |Reflux 3: sodium tetrahydroborate / methanol / 0 - 20 °C / |Schlenk technique 4: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 20 °C / |Schlenk technique 5: sodium hydride / mineral oil; tetrahydrofuran / |Inert atmosphere; |Schlenk technique; |Reflux 6: palladium 10 on activated carbon; hydrogen / ethanol / 20 °C / 3040.2 Torr / |Schlenk technique 7: triethylamine; Methanesulfonyl azide / acetonitrile / 20 °C / |Schlenk technique 8: [Cu(I)(CH3CN)4]PF6; C23H22N2O2; Na[B(3,5-(CF3)2C6H3)4] / dichloromethane / 0.08 h / 25 °C / |Inert atmosphere; |Schlenk technique; |Glovebox View Scheme

1.1: Mg; 1,2-dibromoethane / tetrahydrofuran / 3 h / Heating 1.2: 96 percent / tetrahydrofuran / -78 °C 2.1: 82 percent / pyridinium chlorochromate / CH2Cl2 / 20 °C 3.1: Sudan III; O3 / CH2Cl2 / -78 °C 3.2: 79 percent / PPh3 / CH2Cl2 / -78 - 20 °C 4.1: 81 percent / ammonium acetate / ethanol / 80 °C 5.1: 80 percent / liquid ammonia; Na / tetrahydrofuran / -78 °C 6.1: 52 percent / pyridinium tribromide / ethanol / 55 h / 20 °C View Scheme

1-tert-butyl-4,4,4-tris(dimethylamino)-2,2-bis[tris(dimethylamino)-phosphoranylidenamino]-2Λ54Λ5-catenadi(phosphazene) in benzene Cyclization; 14 h; Heating;

1: potassium hydroxide / ethanol; water / 0 - 20 °C 2: boron trichloride / dichloromethane / 0.5 h / Cooling with ice View Scheme

1: 95 percent Spectr. / 1,4-diazabicyclo[2.2.2]octane / CDCl3 / 504000 h 2: 62 percent / methanol / 72 h 3: 20 percent / H2 / 10 percent Pd/C / ethanol / 6 h / 20 °C / atmospheric pressure View Scheme

ammonia; oxygen; copper(II) nitrate in water; dimethyl sulfoxide T=80°C; P=760.051 Torr; 5 h;