5-甲氧基-2-苯基-1H-吲哚合成路线 （共 43 条）
反应条件
1: toluene / 20 h / 20 °C / |Molecular sieve 2: palladium diacetate; copper diacetate / dimethyl sulfoxide / 45 h / 40 °C / |Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 15, # 15 p. 3812 - 3815
反应条件
methyllithium in tetrahydrofuran T=0 - 20°C;
参考文献
Synthetic Communications, , vol. 35, # 20 p. 2625 - 2632
反应条件
in diethyl ether T=20°C; 2 h;
参考文献
Ding, Hua-Sheng; Yang, Chun-Hao; Xie, Yu-Yuan
Synthetic Communications, 2005 , vol. 35, # 20 p. 2625 - 2632
反应条件
1: [Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2; tricyclo[3.3.1.13,7 ]-decane-1-carboxylic acid; potassium carbonate / m-xylene / 22 h / 120 °C / Inert atmosphere 2: sodium ethanolate / dimethyl sulfoxide / 24 h / 20 - 100 °C / Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 13, # 13 p. 3332 - 3335
反应条件
1: 85 percent / triethylamine / toluene / 1) reflux, 3 h, 2) room temperature, 16 h 2: 80 percent / n-butyllithium / tetrahydrofuran / 20 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 46, # 22 p. 4511 - 4515
反应条件
1: 1-bromo-1-phenyl-ethane With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; zinc in tetrahydrofuran T=50°C; 6 h; Inert atmosphere; 2: 4-methoxybenzenediazonium tetrafluoroborate With zinc dibromide in tetrahydrofuran T=-60 - 25°C; Inert atmosphere; 3: With chloro-trimethyl-silane in tetrahydrofuran T=125°C; 1.5 h; Inert atmosphereMicrowave irradiation; regioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 49 p. 9513 - 9516
反应条件
1: |Acidic conditions 2: palladium dichloride; silver(I) acetate; sulfuric acid / N,N-dimethyl-formamide; acetonitrile / 0.67 h / 100 °C / |Sealed tube; |Microwave irradiation View Scheme
参考文献
Chemistry - An Asian Journal, , vol. 8, # 12 p. 3185 - 3190
反应条件
1: methoxybenzene With sodium azide T=55 - 130°C; 4 h; 2: α-bromoacetophenone T=120 - 130°C; 4 h;
参考文献
Lyakhovnenko; Red'Ko; Aksenova; Aksenov
Russian Journal of Organic Chemistry, 2013 , vol. 49, # 8 p. 1244 - 1245
Zh. Org. Khim., 2013 , vol. 49, # 8 p. 1257 - 1258,2
反应条件
in toluene 1 h; Heating;
参考文献
Baudin, Jean-Bernard; Commenil, Marie-Gabrielle; Julia, Sylvestre A.; Lorne, Robert; Mauclaire, Laurent
Bulletin de la Societe Chimique de France, 1996 , vol. 133, # 4 p. 329 - 350
反应条件
1: benzene / Heating 2: 65 percent / NaNH2-t-BuONa / 2-methyl-propan-2-ol; tetrahydrofuran / 0 deg C -> room temp., 24 h View Scheme
参考文献
Tetrahedron, , vol. 50, # 41 p. 11903 - 11920
