4-甲氧基-4’-氰基联苯合成路线 （共 80 条）
反应条件
palladium; triphenylphosphine in tetrahydrofuran T=70°C; Negishi Coupling; 24 h; Inert atmosphereGreen chemistry; Catalytic behavior;
参考文献
ChemCatChem, , vol. 5, # 4 p. 1011 - 1019
反应条件
1: 97 percent / Mg / tetrahydrofuran / 12 h / Ambient temperature 2: 67 percent / KF / Pd(OAc)2, P(o-Tol)3 / dimethylformamide / 120 °C View Scheme
参考文献
Tetrahedron, , vol. 50, # 28 p. 8301 - 8316
反应条件
palladium diacetate; cesium fluoride; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in tetrahydrofuran T=65°C; Suzuki-Miyaura reaction; 5 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 16, # 45 p. 13390 - 13397
反应条件
1: N-(4-cyanophenyl)acetamide With boron trifluoride-methanol in methanol T=65°C; Inert atmosphere; 2: With tert.-butylnitrite in methanol T=0°C; 1 h; Inert atmosphere; 3: 4-MeOC4H6BF3K With palladium diacetate in methanol T=20°C; Suzuki Coupling; 12.25 h; Inert atmosphere;
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 2-3 p. 463 - 476
反应条件
sodium isopropanolate in isopropyl alcohol 1 h; Heating;
参考文献
Ruolene, Yu. I.; Adomenas, P. V.; Adomenene, O. K.; Denis, G. I.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, p. 1192 - 1195
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1310 - 1314
反应条件
1.1: 73 percent / diethyl ether / 0 - 20 °C 2.1: TBAF / tetrahydrofuran 2.2: 81 percent / TBAF; (t-Bu)3P / [(allyl)PdCl]2 / tetrahydrofuran / 1 h / Heating View Scheme
参考文献
Organic Letters, , vol. 1, # 9 p. 1495 - 1498
反应条件
bathophenanthroline; sodium t-butanolate T=182°C; 6 h; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 132, # 44 p. 15537 - 15539
反应条件
para-chloro-benzonitrile; [2,2']bipyridinyl; NiBr2bipy; potassium iodide in various solvent(s) Further byproducts given;
参考文献
Journal of Organometallic Chemistry, , vol. 393, # 1 p. 137 - 142
反应条件
[2,2']bipyridinyl; NiBr2bipy; potassium iodide in N,N-dimethyl-formamide
参考文献
Journal of Organometallic Chemistry, , vol. 393, # 1 p. 137 - 142
反应条件
C30H21F6N2NiO2P; lithium tert-butylate in tetrahydrofuran T=70°C; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Someya, Chika I.; Weidauer, Maik; Enthaler, Stephan
Catalysis Letters, 2013 , vol. 143, # 5 p. 424 - 431
