bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=80°C; Phenylation; 3 h;

bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=80°C; Stille reaction; 3 h;

bis(η3-allyl-μ-chloropalladium(II)) in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=20°C; 0.0833333 h; Mechanism;

bromine; hexamethyl-distannane; tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane; dichloromethane

1: para-iodobenzonitrile With isopropylmagnesium chloride in tetrahydrofuran; diethyl ether T=-40°C; 1 h; 2: trimethylstannyl chloride in tetrahydrofuran; diethyl ether T=-40 - 20°C;

methyl iodide in ammonia condensation of sodium-dried ammonia into round-bottomed Pyrex flask, addn. of Me3SnCl and Na, then addn. of CNC6H4NMe3I; holding in dark for 0.08 h; quenching by addn. of MeI in excess; evapn. of ammonia, treatment with water, extn. with ether;

tert.-butylnitrite; toluene-4-sulfonic acid in 1,2-dichloro-ethane T=0°C; Sandmeyer Reaction; 4 h; Inert atmosphere;

dichloro bis(acetonitrile) palladium(II) in N,N-dimethyl-formamide byproducts: (CH3)3SnI; Me6Sn2, p-CNC6H4I dissolved in DMF in a flask, catalyst added with stirring, reacted for 10 min at 20°C; water added, extracted with ether, extracts filtered, washed with water, dried with Na2SO4, chromy.(silica gel, hexane/ether 2:1);

tetrakis(triphenylphosphine) palladium(0) in toluene byproducts: Me3SnBr; heated under reflux under N2 for 5 h; various product ratio for variousconditions; low boiling products, including Me3SnBr, taken off under vac., addn. ofn-pentane, filtered, solvent removed, residue fractionally distd., elem. anal.;

in ammonia Inert atmosphereIrradiationliquid NH3;