1-溴-2,4-二硝基苯合成路线 （共 145 条）
反应条件
potassium hydroxide
T=125°C; 10 h; chemoselective reaction;
参考文献
Chatterjee, Tanmay; Ranu, Brindaban C.
Journal of Organic Chemistry, 2013 , vol. 78, # 14 p. 7145 - 7153
参考文献
Um, Ik-Hwan; Im, Li-Ra; Kang, Ji-Sun; Bursey, Samantha S.; Dust, Julian M.
Journal of Organic Chemistry, 2012 , vol. 77, # 21 p. 9738 - 9746
反应条件
triethylamine in benzene
T=25°C; var. oxygen- and nitrogen-containing bases; Rate constantMechanism;
参考文献
Vizgert, R. V.; Sheiko, S. G.; Kulishova, T. P.; Titskii, G. D.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 8.2 p. 1570 - 1573
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 8 p. 1739 - 1743
反应条件
in benzene
T=25°C; var. piperidine conc.; Rate constant;
参考文献
Vizgert, R. V.; Sheiko, S. G.; Kulishova, T. P.; Titskii, G. D.
Journal of Organic Chemistry USSR (English Translation), 1989 , vol. 25, # 8.2 p. 1570 - 1573
Zhurnal Organicheskoi Khimii, 1989 , vol. 25, # 8 p. 1739 - 1743
参考文献
Forrest,J.
Journal of the Chemical Society, 1960 , p. 589 - 592
反应条件
1: dimethylformamide
2: KF / dimethylformamide
3: SnCl2, HCl / diethyl ether
4: NaNO2, H2SO4 / H2O
5: H2O / Heating
6: pyridine
View Scheme
参考文献
Sasaki; Takeuchi; Sato; Takatsu
Molecular crystals and liquid crystals, 1984 , vol. 109, # 2-4 p. 169 - 178
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane; water
T=80°C; 18 h;
参考文献
Dhanak, Dashyant; Knight, Steven David; Moore, Michael Lee; Newlander, Kenneth Alan
Patent: US2009/170882 A1, 2009 ;
Location in patent: Page/Page column 12-13 ;
反应条件
1: NaOEt
2: aq. H2SO4
3: ethanol / (heating)
View Scheme
参考文献
Bluhm,A.L. et al.
Journal of Organic Chemistry, 1964 , vol. 29, p. 636 - 640
参考文献
Fischer,O.
Chemische Berichte, 1896 , vol. 29, p. 1875
参考文献
Austen
Chemische Berichte, 1874 , vol. 7, p. 1250
