3,3’-双(三氟甲基)-1,1’-联苯合成路线 （共 42 条）
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate; silver(l) oxide in methanol
1 h; ultrasound irradiation;
参考文献
Singh, Fateh Veer; Stefani, Helio A.
Synlett, 2008 , # 20 p. 3221 - 3225
反应条件
bis-triphenylphosphine-palladium(II) chloride; triethylamine in tetrahydrofuran
T=80°C; 3 h; Schlenk tubeInert atmosphere;
参考文献
Rao, Maddali L.N.; Giri, Somnath; Jadhav, Deepak N.
Tetrahedron Letters, 2009 , vol. 50, # 45 p. 6133 - 6138
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tetrabutyl ammonium fluoride in tetrahydrofuran; water; toluene
T=100°C; 12 h; Inert atmosphere;
参考文献
Zhang, Zun-Ting; Pitteloud, Jean-Philippe; Cabrera, Laura; Liang, Yong; Toribio, Myrdich; Wnuk, Stanislaw F.
Organic Letters, 2010 , vol. 12, # 4 p. 816 - 819
反应条件
chlorine
T=100 - 130°C; Irradiation.Behandeln des Reaktionsprodukts mit fluessigem HF in Benzotrifluorid in Gegenwart von PCl5 und SbCl5 bei 50grad unter Druck (maximal 17.5 at);
参考文献
Bradsher; Bond
Journal of the American Chemical Society, 1949 , vol. 71, p. 2659
反应条件
pyridine; tetra-n-butylammonium tetrafluoroborate in acetonitrile
T=20°C; Electrolysisiron rod as anode; stainless steel grid as cathode;
参考文献
Gomes, Paulo; Fillon, Hyacinthe; Gosmini, Corinne; Labbe, Eric; Perichon, Jacques
Tetrahedron, 2002 , vol. 58, # 42 p. 8417 - 8424
反应条件
pyridine; tetra-n-butylammonium tetrafluoroborate in acetonitrile
T=20°C; Electrolysisiron rod as anode; stainless steel grid as cathode;
参考文献
Gomes, Paulo; Fillon, Hyacinthe; Gosmini, Corinne; Labbe, Eric; Perichon, Jacques
Tetrahedron, 2002 , vol. 58, # 42 p. 8417 - 8424
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tetrabutyl ammonium fluoride; water in tetrahydrofuran; toluene
T=100°C; 15 h; Inert atmosphere;
参考文献
Pitteloud, Jean-Philippe; Zhang, Zun-Ting; Liang, Yong; Cabrera, Laura; Wnuk, Stanislaw F.
Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8199 - 8212
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tetrabutyl ammonium fluoride; water in tetrahydrofuran; toluene
T=100°C; 5 h; Inert atmosphere;
参考文献
Pitteloud, Jean-Philippe; Zhang, Zun-Ting; Liang, Yong; Cabrera, Laura; Wnuk, Stanislaw F.
Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8199 - 8212
反应条件
1: m-trifluoro-methyl-phenyl-magnesium bromide With bismuth(III) chloride
2: 2-benzoyl-5-bromothiophene With potassium phosphate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide
T=90°C; 1 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Banerjee, Debasis; Dhanorkar, Ritesh J.
Synlett, 2011 , # 9 p. 1324 - 1330
反应条件
tris-(dibenzylideneacetone)dipalladium(0); tetrabutyl ammonium fluoride; water in tetrahydrofuran; toluene
T=100°C; 5 h; Inert atmosphere;
参考文献
Pitteloud, Jean-Philippe; Zhang, Zun-Ting; Liang, Yong; Cabrera, Laura; Wnuk, Stanislaw F.
Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8199 - 8212
