2-(N,N-二甲氨基)苯甲醛合成路线 （共 20 条）
反应条件
potassium carbonate in N,N-dimethyl-formamide T=85°C; 48 h; Inert atmosphere;
参考文献
Castaing, Matthias; Wason, Sacha L.; Estepa, Beatriz; Hooper, Joel F.; Willis, Michael C.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 50 p. 13280 - 13283
Angew. Chem., 2013 , vol. 125, # 50 p. 13522 - 13525,4
反应条件
1: N,N-dimethyl-aniline With n-butyllithium T=0 - 80°C; Inert atmosphere; 2: N,N-dimethyl-formamide in diethyl ether T=0°C; 12 h; Inert atmosphere;
参考文献
Gao, Aihong; Mu, Ying; Zhang, Jingshun; Yao, Wei
European Journal of Inorganic Chemistry, 2009 , # 24 p. 3613 - 3621
反应条件
Dess-Martin periodane in dichloromethane T=0 - 20°C; Inert atmosphere;
参考文献
WO2013/142269 A1, ;
Paragraph 0569; 0570; 0737; 0738 ;
反应条件
diisobutylaluminium hydride in dichloromethane T=-78 - 0°C;
参考文献
Kim, Eunha; Koh, Minseob; Lim, Byung Joon; Park, Seung Bum
Journal of the American Chemical Society, 2011 , vol. 133, # 17 p. 6642 - 6649
参考文献
Bankston, Donald
Synthesis, 2004 , # 2 p. 283 - 289
反应条件
potassium hydrogencarbonate; dimethyl sulfoxide 0.0666667 h; Microwave irradiation;
参考文献
Bratulescu, George
Synthetic Communications, 2008 , vol. 38, # 16 p. 2748 - 2752
反应条件
1: 38 percent / K2CO3 / acetone / Heating 2: 1.) 2.5M BuLi / 1.) Et2O, -40 deg C, 4 h, 2.) Et2O, r.t., overnight View Scheme
参考文献
Australian Journal of Chemistry, , vol. 47, # 9 p. 1751 - 1770
反应条件
1: N,N-dimethyl-formamide With trichlorophosphate T=20°C; Vilsmeier-Haack reaction; 0.166667 h; UV-irradiationNeat (no solvent); 2: N,N-dimethyl-aniline T=100°C; Vilsmeier-Haack reaction; 0.166667 h; UV-irradiationNeat (no solvent);
参考文献
Angewandte Chemie - International Edition, , vol. 49, # 39 p. 7063 - 7067
参考文献
Chemische Berichte, , vol. 37, p. 967,973, 979
Chemische Berichte, , vol. 42, p. 1648 Anm. 6
反应条件
water; toluene-4-sulfonic acid in dimethylsulfoxide-d6; chloroform-d1 T=30°C; half-time life;
参考文献
Chemische Berichte, , vol. 119, # 6 p. 1876 - 1889
