(benzyl)-tri-(butyl)-ammonium chloride; potassium carbonate; palladium diacetate in toluene T=110°C; 24 h;

1: 3-iodoindole-N-SO2-polystyrene With pinacol borane; triethylamine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in 1,4-dioxane T=80°C; 20 h; 2: 1-bromo-4-methoxy-benzene With potassium phosphate; Pd0(tris(tert-butyl)phosphine)2 in N,N-dimethyl-formamide T=80°C; Suzuki coupling reaction; 24 h; 3: With potassium tert-butylate in tetrahydrofuran T=20°C; 6 h;

1: 3-iodoindole-N-SO2-polystyrene With pinacol borane; triethylamine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in 1,4-dioxane T=80°C; 20 h; 2: para-iodoanisole With potassium phosphate; Pd0(tris(tert-butyl)phosphine)2 in N,N-dimethyl-formamide T=80°C; Suzuki coupling reaction; 24 h; 3: With potassium tert-butylate in tetrahydrofuran T=20°C; 6 h;

1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate; palladium diacetate in toluene T=110°C; 48 h;

zinc(II) chloride in ethanol T=100°C; 2 h; Inert atmosphereSchlenk technique;

in N,N-dimethyl-formamide T=100°C; 22 h; Inert atmosphere;

Fe pythalocyanine in toluene RefluxInert atmosphere; regioselective reaction;

lithium hydroxide hydrate; palladium diacetate; bis(1,1-diphenylphosphino)methane in water T=110°C; 18 h; regioselective reaction;

in N,N-dimethyl-formamide T=100°C; 22 h; Inert atmosphere;

tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate in dimethyl sulfoxide T=40°C; 1.75 h;