4-叔-丁基-2-苯基苯酚合成路线 （共 8 条）
反应条件
1: With Pd(OPiv)2; trimethylacetic anhydride in 1,2-dichloro-ethane T=20°C; 0.0833333 h; 2: With trifluorormethanesulfonic acid in 1,2-dichloro-ethane T=25°C; 12 h; 3: With sodium t-butanolate in methanol T=20°C;
参考文献
Journal of the American Chemical Society, , vol. 132, # 2 p. 468 - 469
反应条件
dipotassium hydrogenphosphate trihydrate; 2C2H3O2(1-)*2C6H7N3O2(2-)*2Na(1+)*Pd(2+) in methanol; water T=70°C; Suzuki coupling; 2.5 h;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 27 p. 6733 - 6737
反应条件
1: bromine / dichloromethane / 0 - 20 °C / Inert atmosphere 2: dipotassium hydrogenphosphate trihydrate; 2C2H3O2(1-)*2C6H7N3O2(2-)*2Na(1+)*Pd(2+) / methanol; water / 2.5 h / 70 °C View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 27 p. 6733 - 6737
反应条件
aluminium trichloride T=125°C;
反应条件
hydrogenchloride; iron(III) chloride
反应条件
hydrogenchloride; iron(III) chloride
反应条件
magnesium; trichlorophosphate
T=105 - 115°C; anschliessendes Erhitzen mit 4-tert.-Butyl-phenol auf 115grad bis 205grad;
参考文献
Dow Chem Co.
Patent: US2225285 , 1938 ;
