1-(2,4-二羟基-3,5-二甲基苯基)-乙酮合成路线 （共 8 条）
反应条件
1: BF3*Et2O / 120 °C
2: H2O / tetrahydrofuran / Heating
View Scheme
参考文献
Nicolaou; Vassilikogiannakis, Georgios; Simonsen, Klaus B.; Baran, Phil S.; Zhong, Yong-Li; Vidali, Veroniki P.; Pitsinos, Emmanuel N.; Couladouros, Elias A.
Journal of the American Chemical Society, 2000 , vol. 122, # 13 p. 3071 - 3079
参考文献
Cram
Journal of the American Chemical Society, 1948 , vol. 70, p. 4244,4247
Journal of the American Chemical Society, 1949 , vol. 71, p. 3887
反应条件
1: 1.) HCl; 2.) H2O / 1.) ether; 2.) ether, heating
2: 53 percent / Zn/Hg, HCl / ethanol
3: 1.) ZnCl2, HCl; 2.) H2O / 1.) ether; 2.) ether, heating
View Scheme
参考文献
Morais, Anselmo A.; Fo, Raimundo Braz; Fraiz, Silas V. Jr
Phytochemistry (Elsevier), 1989 , vol. 28, # 1 p. 239 - 242
反应条件
1: 53 percent / Zn/Hg, HCl / ethanol
2: 1.) ZnCl2, HCl; 2.) H2O / 1.) ether; 2.) ether, heating
View Scheme
参考文献
Morais, Anselmo A.; Fo, Raimundo Braz; Fraiz, Silas V. Jr
Phytochemistry (Elsevier), 1989 , vol. 28, # 1 p. 239 - 242
反应条件
hydrogenchloride; diethyl ether; zinc(II) chloride
Erhitzen des Reaktionsprodukts mit Wasser;
参考文献
Hassall; Todd
Journal of the Chemical Society, 1947 , p. 611
反应条件
1: glacial acetic acid; palladium/charcoal / Hydrogenation
2: HCl; ZnCl2; diethyl ether / Erhitzen des Reaktionsprodukts mit Wasser
View Scheme
参考文献
Hassall; Todd
Journal of the Chemical Society, 1947 , p. 611
参考文献
McOmie; Tute
Journal of the Chemical Society, 1958 , p. 3226
反应条件
Kochen des Reaktionsprodukts mit Wasser;
参考文献
Hassall; Todd
Journal of the Chemical Society, 1947 , p. 611
