(E)-11-十六碳烯醛合成路线 （共 13 条）
反应条件
1: 92 percent / TsOH*Py / methanol / 3 h / 45 °C
2: 84 percent / pyridinium chlorochromate / CH2Cl2 / 1 h / 20 °C
View Scheme
参考文献
Cheskis, B. A.; Ivanova, N. M.; Moiseenkov, A. M.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 11 p. 2296 - 2300
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 11 p. 2539 - 2544
反应条件
1: 1) BuLi / 1) HMPA, THF, hexane, 1 h, -50 deg C, 2) 30 min at -50 deg C, 1 h at 20 deg C
2: 61 percent / Li/NH3 / tetrahydrofuran / 1 h / -60 °C
3: 84 percent / pyridinium chlorochromate / CH2Cl2 / 1 h / 20 °C
View Scheme
参考文献
Cheskis, B. A.; Ivanova, N. M.; Moiseenkov, A. M.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 11 p. 2296 - 2300
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 11 p. 2539 - 2544
反应条件
1: 61 percent / Li/NH3 / tetrahydrofuran / 1 h / -60 °C
2: 84 percent / pyridinium chlorochromate / CH2Cl2 / 1 h / 20 °C
View Scheme
参考文献
Cheskis, B. A.; Ivanova, N. M.; Moiseenkov, A. M.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 11 p. 2296 - 2300
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 11 p. 2539 - 2544
