2-苯基-1,3,2-苯并二氧杂戊硼烷合成路线 （共 42 条）
反应条件
palladium diacetate; acetic anhydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone in acetic acid T=90°C; 27 h;
参考文献
Sun, Peng; Zhu, Yan; Yang, Hailong; Yan, Hong; Lu, Linhua; Zhang, Xiang; Mao, Jincheng
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 23 p. 4512 - 4515
反应条件
in hexane T=20°C; 1 h; Molecular sieveInert atmosphereUV-irradiation;
参考文献
Ito, Kazuta; Tamashima, Hiroto; Iwasawa, Nobuharu; Kusama, Hiroyuki
Journal of the American Chemical Society, 2011 , vol. 133, # 11 p. 3716 - 3719
反应条件
CuF2; Ni(PCy3)2Cl2; potassium tert-butylate; tri-cyclo-hexyl-phosphine in 1,4-dioxane T=110°C; Suzuki-Miyaura coupling; 20 h; Inert atmosphere;
参考文献
Yu, Da-Gang; Yu, Miao; Guan, Bing-Tao; Li, Bi-Jie; Zheng, Yang; Wu, Zhen-Hua; Shi, Zhang-Jie
Organic Letters, 2009 , vol. 11, # 15 p. 3374 - 3377
反应条件
1: With sodium hydride in tetrahydrofuran T=20°C; Suzuki-Miyaura coupling; 0.0833333 h; Inert atmosphere; 2: With triethyl borane in tetrahydrofuran; hexane T=20°C; Suzuki-Miyaura coupling; 0.0833333 h; Inert atmosphere; 3: With [Ni0(1,5-cyclooctadiene)2]; tri-cyclo-hexyl-phosphine in tetrahydrofuran; hexane; o-xylene T=110°C; Suzuki-Miyaura coupling; 24 h; Inert atmosphere;
参考文献
Yu, Da-Gang; Shi, Zhang-Jie
Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7097 - 7100
反应条件
triphenyl phosphite; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in 1,4-dioxane T=80°C; Suzuki-Miyaura coupling; 6 h;
参考文献
Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao
European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993
反应条件
potassium carbonate; aluminum oxide; ruthenium in ethylene glycol dimethyl ether; water T=80°C; Suzuki-Miyaura-type cross coupling reaction; 12 h;
参考文献
Na, Youngim; Park, Soyoung; Han, Soo Bong; Han, Hoon; Ko, Sangwon; Chang, Sukbok
Journal of the American Chemical Society, 2004 , vol. 126, # 1 p. 250 - 258
反应条件
sodium acetate T=20°C; 20 h;
参考文献
Tetrahedron, , vol. 61, # 7 p. 1765 - 1771
反应条件
sodium methylate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; copper(l) iodide in ethylene glycol dimethyl ether; acetonitrile T=60°C; 2 h;
参考文献
Kang, Suk-Ku; Ryu, Hyung-Chul; Son, Hoe-Joo
Synlett, 1998 , # 7 p. 771 - 773
反应条件
boron trifluoride diethyl etherate in chloroform
T=20°C; 18 h;
参考文献
Spitler, Eric L.; Dichtel, William R.
Nature Chemistry, 2010 , vol. 2, # 8 p. 672 - 677
反应条件
catalyst: [Ir(COD)(OMe)]2+di-tert-butyl-bipyridine in neat (no solvent)
120°C, 24 h;
参考文献
Liskey, Carl W.; Wei, Carolyn S.; Pahls, Dale R.; Hartwig, John F.
Chemical Communications, 2009 , # 37 p. 5603 - 5605
