5-雄烯-3,17-二酮合成路线 （共 19 条）
反应条件
Oppenauer oxidation;
参考文献
Yao, Zhiyi; Xu, Yingjun; Zhang, Minmin; Jiang, Sheng; Nicklaus, Marc C.; Liao, Chenzhong
Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 1 p. 475 - 478
反应条件
potassium hydroxide; sodium hydrogencarbonate; acetic acid in ethylene glycol dimethyl ether 15 h; Ambient temperature;
参考文献
D'Incan, E.; Viout, P.
Tetrahedron, 1984 , vol. 40, # 18 p. 3421 - 3424
反应条件
Celite; pyridinium chlorochromate in dichloromethane 3.5 h; Ambient temperature; Yields of byproduct given;
参考文献
Jiang, S. Anna; Xiao, Changhe; Morrison, Harry
Journal of Organic Chemistry, 1996 , vol. 61, # 20 p. 7045 - 7055
反应条件
zinc in ethanol; water T=20°C; 72 h; Inert atmosphere;
参考文献
Morton, Daniel; Dick, Allison R.; Ghosh, Debashis; Davies, Huw M. L.
Chemical Communications, 2012 , vol. 48, # 47 p. 5838 - 5840
反应条件
sodium hydroxide; 3-oxo-Δ5-steroid isomerase in methanol; water pH 5.0 to 5.1; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 112, # 5 p. 1996 - 1998
反应条件
sodium acetate; acetic acid in methanol; water T=25°C; μ = 0.09; Rate constantMechanism;
参考文献
Journal of the American Chemical Society, , vol. 113, # 10 p. 3838 - 3842
反应条件
2,2'-bipyridylchromium peroxide in benzene 3 h; Heatingeffect of various chromium(VI) based oxidants; Product distribution;
参考文献
Tetrahedron, , vol. 42, # 2 p. 719 - 726
反应条件
bromine; acetic acid anschliessendes Behandeln mit CrO3 und Erwaermen des Reaktionsprodukts mit Zink-Pulver und Methanol;
反应条件
nachfolgendes Behandeln mit CrO3 und Erwaermen des Reaktionsprodukts mit Zink-Pulver und Methanol;
参考文献
Chemische Berichte, , vol. 69, p. 882,887
反应条件
weitere Verbindung: Essigsaeure; Kochen des Reaktionsprodukts in Methanol mit Zink-Pulver;
参考文献
GB501421 , ;
FR847487 , ;
