3-乙基环戊-2-烯-1-酮合成路线 （共 9 条）
反应条件
1: With C9H19NO2*C50H57O4P in anhydrous butyl ether T=60°C; 0.0333333 - 0.0833333 h; 2: With C15H23NO4 in anhydrous butyl ether T=60°C; 48 h; Product distribution / selectivity;
参考文献
Rueping, Magnus; Sugiono, Erli; Schoepke, Fenja R.
Synlett, 2010 , # 6 p. 852 - 865
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene; mercury(II) oxide in dichloromethane
参考文献
Trost, Barry M.; Murayama, Eigoro
Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6529 - 6530
反应条件
in tetrahydrofuran; diethyl ether
T=20°C; 34 h;
参考文献
Martin, Nolwenn J. A.; List, Benjamin
Journal of the American Chemical Society, 2006 , vol. 128, # 41 p. 13368 - 13369
反应条件
1: 65 percent / dimethyl(methylthio)sulfonium fluoroborate / CH2Cl2 / -30 - -20 °C
2: 94 percent / HgO, DBU / CH2Cl2
View Scheme
参考文献
Trost, Barry M.; Murayama, Eigoro
Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6529 - 6530
参考文献
Ube Industries, Ltd.
Patent: US3953514 A1, 1976 ;
反应条件
1: Ph2CO / Irradiation
2: TsOH / toluene
View Scheme
参考文献
Reinfried,R. et al.
Helvetica Chimica Acta, 1971 , vol. 54, p. 1517 - 1531
反应条件
1: 71 percent / ethyl acetate / 1) r.t., 30 min, 2) reflux, 4 h
2: 87 percent / 5percent EtOH / toluene / 12 h / Heating
View Scheme
参考文献
Bestmann, Hans Juergen; Schade, Gerold; Luetke, Harry; Moenius, Thomas
Chemische Berichte, 1985 , vol. 118, # 7 p. 2640 - 2658
反应条件
in tetrahydrofuran
T=20°C;
参考文献
Vuagnoux-D'Augustin, Magali; Alexakis, Alexandre
Chemistry - A European Journal, 2007 , vol. 13, # 34 p. 9647 - 9662
参考文献
Reinfried,R. et al.
Helvetica Chimica Acta, 1971 , vol. 54, p. 1517 - 1531
